Metathesis polymer based on 5-trimethylsilylbicyclo[2.2.2]oct-2-ene: Synthesis and gas-transport properties
A new silicon-containing bicyclic monomer 5-trimethylsilylbicyclo[2.2.2]oct-2-ene has been synthesized, and its metathesis polymerization and gas transport properties of the polymer based on it have been studied. The monomer is synthesized by the two-step scheme using the Diels–Alder reaction from 1...
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| Veröffentlicht in: | Polymer science. Series B 2016-11, Vol.58 (6), p.659-664 |
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| container_title | Polymer science. Series B |
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| creator | Alent’ev, D. A. Bermeshev, M. V. Starannikova, L. E. Solopchenko, A. V. Yampol’skii, Yu. P. Finkelshtein, E. Sh |
| description | A new silicon-containing bicyclic monomer 5-trimethylsilylbicyclo[2.2.2]oct-2-ene has been synthesized, and its metathesis polymerization and gas transport properties of the polymer based on it have been studied. The monomer is synthesized by the two-step scheme using the Diels–Alder reaction from 1,3-cyclohexadiene and vinyltrichlorosilane followed by methylation with a Grignard reagent. The resulting 5-trimethylsilylbicyclo[ 2.2.2]oct-2-ene is inactive in metathesis homopolymerization in the presence of first- and second- generation Grubbs catalysts and a Hoveyda–Grubbs catalyst, but it slowly polymerizes when norbornene is present in the reaction mixture. The high-molecular-mass copolymer (
M
w
= 3.0 × 10
5
,
M
w
/
M
n
= 2.8) of 5-trimethylsilylbicyclo[2.2.2]oct-2-ene and norbornene possesses good film-forming properties, and its glass transition temperature is 126°C. The gas-transport properties of the copolymer have been studied. |
| doi_str_mv | 10.1134/S1560090416060014 |
| format | Article |
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M
w
= 3.0 × 10
5
,
M
w
/
M
n
= 2.8) of 5-trimethylsilylbicyclo[2.2.2]oct-2-ene and norbornene possesses good film-forming properties, and its glass transition temperature is 126°C. The gas-transport properties of the copolymer have been studied.</description><identifier>ISSN: 1560-0904</identifier><identifier>EISSN: 1555-6123</identifier><identifier>DOI: 10.1134/S1560090416060014</identifier><language>eng</language><publisher>Moscow: Pleiades Publishing</publisher><subject>Catalysis ; Catalysts ; Chemistry ; Chemistry and Materials Science ; Copolymers ; Decomposition reactions ; Gas transport ; Glass transition temperature ; Metathesis ; Monomers ; Polymer Sciences ; Polymerization ; Polymers ; Reagents ; Synthesis ; Synthesis (chemistry) ; Transport properties</subject><ispartof>Polymer science. Series B, 2016-11, Vol.58 (6), p.659-664</ispartof><rights>Pleiades Publishing, Ltd. 2016</rights><rights>Copyright Springer Science & Business Media 2016</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-26a6f0cea768e32ed4d95c70ad2bf5cb9205f1d48a8b78a7e2ad18708351e2763</citedby><cites>FETCH-LOGICAL-c349t-26a6f0cea768e32ed4d95c70ad2bf5cb9205f1d48a8b78a7e2ad18708351e2763</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1134/S1560090416060014$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1134/S1560090416060014$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Alent’ev, D. A.</creatorcontrib><creatorcontrib>Bermeshev, M. V.</creatorcontrib><creatorcontrib>Starannikova, L. E.</creatorcontrib><creatorcontrib>Solopchenko, A. V.</creatorcontrib><creatorcontrib>Yampol’skii, Yu. P.</creatorcontrib><creatorcontrib>Finkelshtein, E. Sh</creatorcontrib><title>Metathesis polymer based on 5-trimethylsilylbicyclo[2.2.2]oct-2-ene: Synthesis and gas-transport properties</title><title>Polymer science. Series B</title><addtitle>Polym. Sci. Ser. B</addtitle><description>A new silicon-containing bicyclic monomer 5-trimethylsilylbicyclo[2.2.2]oct-2-ene has been synthesized, and its metathesis polymerization and gas transport properties of the polymer based on it have been studied. The monomer is synthesized by the two-step scheme using the Diels–Alder reaction from 1,3-cyclohexadiene and vinyltrichlorosilane followed by methylation with a Grignard reagent. The resulting 5-trimethylsilylbicyclo[ 2.2.2]oct-2-ene is inactive in metathesis homopolymerization in the presence of first- and second- generation Grubbs catalysts and a Hoveyda–Grubbs catalyst, but it slowly polymerizes when norbornene is present in the reaction mixture. The high-molecular-mass copolymer (
M
w
= 3.0 × 10
5
,
M
w
/
M
n
= 2.8) of 5-trimethylsilylbicyclo[2.2.2]oct-2-ene and norbornene possesses good film-forming properties, and its glass transition temperature is 126°C. The gas-transport properties of the copolymer have been studied.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Copolymers</subject><subject>Decomposition reactions</subject><subject>Gas transport</subject><subject>Glass transition temperature</subject><subject>Metathesis</subject><subject>Monomers</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Polymers</subject><subject>Reagents</subject><subject>Synthesis</subject><subject>Synthesis (chemistry)</subject><subject>Transport properties</subject><issn>1560-0904</issn><issn>1555-6123</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNp1kT1PwzAQhi0EEqj0B7BFYmEJ-Oz4I2yo4ksqYihMCEWOc2kDaRzsdMi_x1U7IBDn4V7Jz_ue5SPkDOglAM-uFiAkpTnNQNIoIDsgJyCESCUwfrjVkqbb-2MyDeGDxuI5B8hPyOcTDmZYYWhC0rt2XKNPShOwSlyXiHTwzRqH1diGph3bsrGjbd0bu4zn3dkhZSl2eJ0sxm6fYboqWZoQjaYLvfND0nvXox8aDKfkqDZtwOm-T8jr3e3L7CGdP98_zm7mqeVZHjOlkTW1aJTUyBlWWZULq6ipWFkLW-aMihqqTBtdKm0UMlOBVlRzAciU5BNyscuNo782GIZi3QSLbWs6dJtQgM55TpVSOqLnv9APt_FdfF2kNNWgZYQnBHaU9S4Ej3XRx38xfiyAFtsNFH82ED1s5wmR7ZbofyT_a_oGuu2HhA</recordid><startdate>20161101</startdate><enddate>20161101</enddate><creator>Alent’ev, D. A.</creator><creator>Bermeshev, M. V.</creator><creator>Starannikova, L. E.</creator><creator>Solopchenko, A. V.</creator><creator>Yampol’skii, Yu. P.</creator><creator>Finkelshtein, E. Sh</creator><general>Pleiades Publishing</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20161101</creationdate><title>Metathesis polymer based on 5-trimethylsilylbicyclo[2.2.2]oct-2-ene: Synthesis and gas-transport properties</title><author>Alent’ev, D. A. ; Bermeshev, M. V. ; Starannikova, L. E. ; Solopchenko, A. V. ; Yampol’skii, Yu. P. ; Finkelshtein, E. Sh</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-26a6f0cea768e32ed4d95c70ad2bf5cb9205f1d48a8b78a7e2ad18708351e2763</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Copolymers</topic><topic>Decomposition reactions</topic><topic>Gas transport</topic><topic>Glass transition temperature</topic><topic>Metathesis</topic><topic>Monomers</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Polymers</topic><topic>Reagents</topic><topic>Synthesis</topic><topic>Synthesis (chemistry)</topic><topic>Transport properties</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Alent’ev, D. A.</creatorcontrib><creatorcontrib>Bermeshev, M. V.</creatorcontrib><creatorcontrib>Starannikova, L. E.</creatorcontrib><creatorcontrib>Solopchenko, A. V.</creatorcontrib><creatorcontrib>Yampol’skii, Yu. P.</creatorcontrib><creatorcontrib>Finkelshtein, E. Sh</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Polymer science. Series B</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Alent’ev, D. A.</au><au>Bermeshev, M. V.</au><au>Starannikova, L. E.</au><au>Solopchenko, A. V.</au><au>Yampol’skii, Yu. P.</au><au>Finkelshtein, E. Sh</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Metathesis polymer based on 5-trimethylsilylbicyclo[2.2.2]oct-2-ene: Synthesis and gas-transport properties</atitle><jtitle>Polymer science. Series B</jtitle><stitle>Polym. Sci. Ser. B</stitle><date>2016-11-01</date><risdate>2016</risdate><volume>58</volume><issue>6</issue><spage>659</spage><epage>664</epage><pages>659-664</pages><issn>1560-0904</issn><eissn>1555-6123</eissn><abstract>A new silicon-containing bicyclic monomer 5-trimethylsilylbicyclo[2.2.2]oct-2-ene has been synthesized, and its metathesis polymerization and gas transport properties of the polymer based on it have been studied. The monomer is synthesized by the two-step scheme using the Diels–Alder reaction from 1,3-cyclohexadiene and vinyltrichlorosilane followed by methylation with a Grignard reagent. The resulting 5-trimethylsilylbicyclo[ 2.2.2]oct-2-ene is inactive in metathesis homopolymerization in the presence of first- and second- generation Grubbs catalysts and a Hoveyda–Grubbs catalyst, but it slowly polymerizes when norbornene is present in the reaction mixture. The high-molecular-mass copolymer (
M
w
= 3.0 × 10
5
,
M
w
/
M
n
= 2.8) of 5-trimethylsilylbicyclo[2.2.2]oct-2-ene and norbornene possesses good film-forming properties, and its glass transition temperature is 126°C. The gas-transport properties of the copolymer have been studied.</abstract><cop>Moscow</cop><pub>Pleiades Publishing</pub><doi>10.1134/S1560090416060014</doi><tpages>6</tpages></addata></record> |
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| subjects | Catalysis Catalysts Chemistry Chemistry and Materials Science Copolymers Decomposition reactions Gas transport Glass transition temperature Metathesis Monomers Polymer Sciences Polymerization Polymers Reagents Synthesis Synthesis (chemistry) Transport properties |
| title | Metathesis polymer based on 5-trimethylsilylbicyclo[2.2.2]oct-2-ene: Synthesis and gas-transport properties |
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