Vinylogy in nitronates: utilization of α-aryl conjugated nitroolefins as a nucleophile for a highly stereoselective aza-Henry reaction

The vinylogous reactivity of α,β-disubstituted nitroolefins was uncovered through the facile generation of the corresponding α-substituted vinylogous nitronates and their use in the development of a highly diastereo- and enantioselective aza-Henry reaction with N-Boc aldimines under the catalysis of...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-03, Vol.51 (21), p.4437-4439
Hauptverfasser:	Oyaizu, Keigo, Uraguchi, Daisuke, Ooi, Takashi
Format:	Artikel
Sprache:	eng
Schlagworte:	Alkenes - chemistry Betaine - chemistry Betaines Bonding Carbon Catalysis Imines - chemistry Nitro Compounds - chemistry Nucleophiles Organic compounds Stereoisomerism Utilization Vinyl Compounds - chemistry
Online-Zugang:	Volltext
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