Enantioselective synthesis of arylglycine derivatives by direct C-H oxidative cross-coupling

A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C-H arylation of N-aryl glycine esters with aryl boric acids in the presence of a chiral Pd(II)-catalyst has been developed. This work successfully integrates the direct C-H oxidation with asymmetric arylation and...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2015-01, Vol.51 (5), p.832-835
Hauptverfasser:	Wei, Xiao-Hong, Wang, Gang-Wei, Yang, Shang-Dong
Format:	Artikel
Sprache:	eng
Schlagworte:	Aromatic compounds Asymmetry Boric acids Carbon - chemistry Chemistry Techniques, Synthetic Cross coupling Derivatives Esters Glycine Glycine - analogs & derivatives Glycine - chemical synthesis Glycine - chemistry Hydrogen - chemistry Oxidation-Reduction Stereoisomerism Substrate Specificity Synthesis
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creator	Wei, Xiao-Hong Wang, Gang-Wei Yang, Shang-Dong
description	A new method for the synthesis of chiral α-amino acid derivatives by enantioselective C-H arylation of N-aryl glycine esters with aryl boric acids in the presence of a chiral Pd(II)-catalyst has been developed. This work successfully integrates the direct C-H oxidation with asymmetric arylation and exhibits excellent enantioselectivity.
doi_str_mv	10.1039/c4cc07361d
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source	MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Aromatic compounds Asymmetry Boric acids Carbon - chemistry Chemistry Techniques, Synthetic Cross coupling Derivatives Esters Glycine Glycine - analogs & derivatives Glycine - chemical synthesis Glycine - chemistry Hydrogen - chemistry Oxidation-Reduction Stereoisomerism Substrate Specificity Synthesis
title	Enantioselective synthesis of arylglycine derivatives by direct C-H oxidative cross-coupling
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