Panchromatic absorbers for solar light-harvesting

A set of panchromatic absorbers exhibiting long excited-state lifetimes in both polar and nonpolar media has been prepared. The architectures are based on a porphyrin strongly coupled electronically to 1-4 perylene-monoimides via ethyne linkers. The constructs should find utility in molecular solar-...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-12, Vol.50 (93), p.14512-14515
Hauptverfasser: Alexy, Eric J, Yuen, Jonathan M, Chandrashaker, Vanampally, Diers, James R, Kirmaier, Christine, Bocian, David F, Holten, Dewey, Lindsey, Jonathan S
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Sprache:eng
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Zusammenfassung:A set of panchromatic absorbers exhibiting long excited-state lifetimes in both polar and nonpolar media has been prepared. The architectures are based on a porphyrin strongly coupled electronically to 1-4 perylene-monoimides via ethyne linkers. The constructs should find utility in molecular solar-conversion systems.
ISSN:1359-7345
1364-548X
DOI:10.1039/c4cc06853j