Ru(ii)-Pheox-catalyzed Si-H insertion reaction: construction of enantioenriched carbon and silicon centers

We established a highly enantioselective Si-H insertion reaction to construct chiral centers at the carbon and silicon atoms, using a Ru(ii)-pheox catalyst. The catalytic asymmetric Si-H insertion reaction of α-methyl-α-diazoesters proceeded smoothly with excellent stereoinduction at both the neighb...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2017, Vol.53 (26), p.3753-3756
Hauptverfasser:	Nakagawa, Yoko, Chanthamath, Soda, Fujisawa, Ikuhide, Shibatomi, Kazutaka, Iwasa, Seiji
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Carbon Catalysis Catalysts Insertion Silicon
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creator	Nakagawa, Yoko Chanthamath, Soda Fujisawa, Ikuhide Shibatomi, Kazutaka Iwasa, Seiji
description	We established a highly enantioselective Si-H insertion reaction to construct chiral centers at the carbon and silicon atoms, using a Ru(ii)-pheox catalyst. The catalytic asymmetric Si-H insertion reaction of α-methyl-α-diazoesters proceeded smoothly with excellent stereoinduction at both the neighboring carbon and silicon atoms (up to 99% yield and 99% ee).
doi_str_mv	10.1039/c7cc01070b
format	Article
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Asymmetry Carbon Catalysis Catalysts Insertion Silicon
title	Ru(ii)-Pheox-catalyzed Si-H insertion reaction: construction of enantioenriched carbon and silicon centers
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