Piezochromic luminescence behaviors of two new benzothiazole-enamido boron difluoride complexes: intra- and inter-molecular effects induced by hydrostatic compression

Two new propeller-shaped benzothiazole-enamide boron difluoride complexes exhibiting piezochromic luminescence upon mechanical grinding or hydrostatic compression were prepared. The two analogues displayed the red shift in luminescence under high pressure, while compound 2 with ICT effects showed a...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2015-05, Vol.51 (35), p.7497-7500
Hauptverfasser: Wang, Xiaoqing, Liu, Qingsong, Yan, Hui, Liu, Zhipeng, Yao, Mingguang, Zhang, Qingfu, Gong, Shuwen, He, Weijiang
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container_end_page 7500
container_issue 35
container_start_page 7497
container_title Chemical communications (Cambridge, England)
container_volume 51
creator Wang, Xiaoqing
Liu, Qingsong
Yan, Hui
Liu, Zhipeng
Yao, Mingguang
Zhang, Qingfu
Gong, Shuwen
He, Weijiang
description Two new propeller-shaped benzothiazole-enamide boron difluoride complexes exhibiting piezochromic luminescence upon mechanical grinding or hydrostatic compression were prepared. The two analogues displayed the red shift in luminescence under high pressure, while compound 2 with ICT effects showed a more sensitive piezochromic response at low pressure (
doi_str_mv 10.1039/c5cc01902h
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The two analogues displayed the red shift in luminescence under high pressure, while compound 2 with ICT effects showed a more sensitive piezochromic response at low pressure (&lt;1.5 GPa). The different piezochromic luminescence behaviors of these compounds were investigated.</abstract><cop>England</cop><pmid>25828923</pmid><doi>10.1039/c5cc01902h</doi><tpages>4</tpages></addata></record>
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Benzothiazoles - chemistry
Boron
Boron Compounds - chemistry
Compressing
Difluorides
Doppler effect
Fluorescent Dyes - chemistry
Hydrostatics
Low pressure
Luminescence
Pressure
Red shift
Spectrometry, Fluorescence
title Piezochromic luminescence behaviors of two new benzothiazole-enamido boron difluoride complexes: intra- and inter-molecular effects induced by hydrostatic compression
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