Specific distribution of orientated C70-fullerene triggered by solvent-tuned macrocycle adlayer
The precise localization of organic molecules in controllable positions is an important step towards constructing functional nanostructures via the bottom-up strategy. Herein, supramolecularly organized C70-fullerene assemblies on macrocycle-modified surfaces were investigated using scanning tunneli...
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| Veröffentlicht in: | Nano research 2017-03, Vol.10 (3), p.991-1000 |
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| creator | Geng, Yanfang Li, Ping Xue, Jindong Luo, Dapeng Zhang, Junyong Shu, Lijin Deng, Ke Xie, Jingli Zeng, Qingdao |
| description | The precise localization of organic molecules in controllable positions is an important step towards constructing functional nanostructures via the bottom-up strategy. Herein, supramolecularly organized C70-fullerene assemblies on macrocycle-modified surfaces were investigated using scanning tunneling microscopy （STM） in combination with theoretical calculations. The results revealed that an up-assembly of C70-fullerene adlayers was successfully formed on top of the bottom macrocycle arrays. Density functional theory （DFT） calculations confirmed that the macrocycle networks along with the co-adsorbed solvent 1-phenyloctane served as a selective template for trapping C70-fullerene molecules in the spectral sites and acted as a support for the C70-fullerene molecules. The periodical distribution of the C70-fullerene molecules should facilitate understanding of the strong dependence of the arrangement of C70-fullerene upon the specific interactions （apart from spatial recognition） derived from modification of the sub-monolayers. |
| doi_str_mv | 10.1007/s12274-016-1358-5 |
| format | Article |
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Herein, supramolecularly organized C70-fullerene assemblies on macrocycle-modified surfaces were investigated using scanning tunneling microscopy （STM） in combination with theoretical calculations. The results revealed that an up-assembly of C70-fullerene adlayers was successfully formed on top of the bottom macrocycle arrays. Density functional theory （DFT） calculations confirmed that the macrocycle networks along with the co-adsorbed solvent 1-phenyloctane served as a selective template for trapping C70-fullerene molecules in the spectral sites and acted as a support for the C70-fullerene molecules. The periodical distribution of the C70-fullerene molecules should facilitate understanding of the strong dependence of the arrangement of C70-fullerene upon the specific interactions （apart from spatial recognition） derived from modification of the sub-monolayers.</description><identifier>ISSN: 1998-0124</identifier><identifier>EISSN: 1998-0000</identifier><identifier>DOI: 10.1007/s12274-016-1358-5</identifier><language>eng</language><publisher>Beijing: Tsinghua University Press</publisher><subject>Arrays ; Atomic/Molecular Structure and Spectra ; Biomedicine ; Biotechnology ; Chemistry and Materials Science ; Condensed Matter Physics ; Density functional theory ; Fullerenes ; Localization ; Macrocyclic compounds ; Materials Science ; Mathematical analysis ; Nanostructure ; Nanotechnology ; Organic chemistry ; Research Article ; Scanning tunneling microscopy ; Short term memory ; Solvents ; Spatial distribution ; Spectra ; Strategy</subject><ispartof>Nano research, 2017-03, Vol.10 (3), p.991-1000</ispartof><rights>Tsinghua University Press and Springer-Verlag Berlin Heidelberg 2016</rights><rights>Nano Research is a copyright of Springer, (2016). All Rights Reserved.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c475t-41a76f6b97472a5d6f0e2e9916ad0243c58c538afa1ab9c48553766f36e8f6e23</citedby><cites>FETCH-LOGICAL-c475t-41a76f6b97472a5d6f0e2e9916ad0243c58c538afa1ab9c48553766f36e8f6e23</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Uhttp://image.cqvip.com/vip1000/qk/71233X/71233X.jpg</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s12274-016-1358-5$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s12274-016-1358-5$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Geng, Yanfang</creatorcontrib><creatorcontrib>Li, Ping</creatorcontrib><creatorcontrib>Xue, Jindong</creatorcontrib><creatorcontrib>Luo, Dapeng</creatorcontrib><creatorcontrib>Zhang, Junyong</creatorcontrib><creatorcontrib>Shu, Lijin</creatorcontrib><creatorcontrib>Deng, Ke</creatorcontrib><creatorcontrib>Xie, Jingli</creatorcontrib><creatorcontrib>Zeng, Qingdao</creatorcontrib><title>Specific distribution of orientated C70-fullerene triggered by solvent-tuned macrocycle adlayer</title><title>Nano research</title><addtitle>Nano Res</addtitle><addtitle>Nano Research</addtitle><description>The precise localization of organic molecules in controllable positions is an important step towards constructing functional nanostructures via the bottom-up strategy. Herein, supramolecularly organized C70-fullerene assemblies on macrocycle-modified surfaces were investigated using scanning tunneling microscopy （STM） in combination with theoretical calculations. The results revealed that an up-assembly of C70-fullerene adlayers was successfully formed on top of the bottom macrocycle arrays. Density functional theory （DFT） calculations confirmed that the macrocycle networks along with the co-adsorbed solvent 1-phenyloctane served as a selective template for trapping C70-fullerene molecules in the spectral sites and acted as a support for the C70-fullerene molecules. The periodical distribution of the C70-fullerene molecules should facilitate understanding of the strong dependence of the arrangement of C70-fullerene upon the specific interactions （apart from spatial recognition） derived from modification of the sub-monolayers.</description><subject>Arrays</subject><subject>Atomic/Molecular Structure and Spectra</subject><subject>Biomedicine</subject><subject>Biotechnology</subject><subject>Chemistry and Materials Science</subject><subject>Condensed Matter Physics</subject><subject>Density functional theory</subject><subject>Fullerenes</subject><subject>Localization</subject><subject>Macrocyclic compounds</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Nanostructure</subject><subject>Nanotechnology</subject><subject>Organic chemistry</subject><subject>Research Article</subject><subject>Scanning tunneling microscopy</subject><subject>Short term memory</subject><subject>Solvents</subject><subject>Spatial 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Qingdao</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Specific distribution of orientated C70-fullerene triggered by solvent-tuned macrocycle adlayer</atitle><jtitle>Nano research</jtitle><stitle>Nano Res</stitle><addtitle>Nano Research</addtitle><date>2017-03-01</date><risdate>2017</risdate><volume>10</volume><issue>3</issue><spage>991</spage><epage>1000</epage><pages>991-1000</pages><issn>1998-0124</issn><eissn>1998-0000</eissn><abstract>The precise localization of organic molecules in controllable positions is an important step towards constructing functional nanostructures via the bottom-up strategy. Herein, supramolecularly organized C70-fullerene assemblies on macrocycle-modified surfaces were investigated using scanning tunneling microscopy （STM） in combination with theoretical calculations. The results revealed that an up-assembly of C70-fullerene adlayers was successfully formed on top of the bottom macrocycle arrays. Density functional theory （DFT） calculations confirmed that the macrocycle networks along with the co-adsorbed solvent 1-phenyloctane served as a selective template for trapping C70-fullerene molecules in the spectral sites and acted as a support for the C70-fullerene molecules. The periodical distribution of the C70-fullerene molecules should facilitate understanding of the strong dependence of the arrangement of C70-fullerene upon the specific interactions （apart from spatial recognition） derived from modification of the sub-monolayers.</abstract><cop>Beijing</cop><pub>Tsinghua University Press</pub><doi>10.1007/s12274-016-1358-5</doi><tpages>10</tpages></addata></record> |
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| identifier | ISSN: 1998-0124 |
| ispartof | Nano research, 2017-03, Vol.10 (3), p.991-1000 |
| issn | 1998-0124 1998-0000 |
| language | eng |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Arrays Atomic/Molecular Structure and Spectra Biomedicine Biotechnology Chemistry and Materials Science Condensed Matter Physics Density functional theory Fullerenes Localization Macrocyclic compounds Materials Science Mathematical analysis Nanostructure Nanotechnology Organic chemistry Research Article Scanning tunneling microscopy Short term memory Solvents Spatial distribution Spectra Strategy |
| title | Specific distribution of orientated C70-fullerene triggered by solvent-tuned macrocycle adlayer |
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