A Sugar-Derived Room-Temperature Sodium Sulfur Battery with Long Term Cycling Stability
We demonstrate a room-temperature sodium sulfur battery based on a confining microporous carbon template derived from sucrose that delivers a reversible capacity over 700 mAh/gS at 0.1C rates, maintaining 370 mAh/gS at 10 times higher rates of 1C. Cycling at 1C rates reveals retention of over 300 mA...
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| Veröffentlicht in: | Nano letters 2017-03, Vol.17 (3), p.1863-1869 |
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| container_issue | 3 |
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| container_title | Nano letters |
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| creator | Carter, Rachel Oakes, Landon Douglas, Anna Muralidharan, Nitin Cohn, Adam P Pint, Cary L |
| description | We demonstrate a room-temperature sodium sulfur battery based on a confining microporous carbon template derived from sucrose that delivers a reversible capacity over 700 mAh/gS at 0.1C rates, maintaining 370 mAh/gS at 10 times higher rates of 1C. Cycling at 1C rates reveals retention of over 300 mAh/gS capacity across 1500 cycles with Coulombic efficiency >98% due to microporous sulfur confinement and stability of the sodium metal anode in a glyme-based electrolyte. We show sucrose to be an ideal platform to develop microporous carbon capable of mitigating electrode–electrolyte reactivity and loss of soluble intermediate discharge products. In a manner parallel to the low-cost materials of the traditional sodium beta battery, our work demonstrates the combination of table sugar, sulfur, and sodium, all of which are cheap and earth abundant, for a high-performance stable room-temperature sodium sulfur battery. |
| doi_str_mv | 10.1021/acs.nanolett.6b05172 |
| format | Article |
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| ispartof | Nano letters, 2017-03, Vol.17 (3), p.1863-1869 |
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| language | eng |
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| source | ACS Publications |
| subjects | Carbon Confinement Cycles Sodium Sodium sulfur batteries Stability Sucrose Sulfur |
| title | A Sugar-Derived Room-Temperature Sodium Sulfur Battery with Long Term Cycling Stability |
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