The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

The corrole and ferrocene marriage: 5,10,15-triferrocenylcorrolato Cu

Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained sugges...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-01, Vol.50 (31), p.4076-4078
Hauptverfasser: Pomarico, Giuseppe, Vecchi, Andrea, Mandoj, Federica, Bortolini, Olga, Cicero, Daniel O, Galloni, Pierluca, Paolesse, Roberto
Format: Artikel
Sprache:eng
Schlagworte:
Coordination Complexes - chemistry
Copper
Copper - chemistry
Derivatives
Eccentricity
Electrochemistry
Ferrocenes
Ferrous Compounds - chemistry
Magnetic Resonance Spectroscopy
Metallocenes
Porphyrins - chemistry
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Beschreibung
Zusammenfassung:Two synthetic routes have been defined for the preparation of a 5,10,15-triferrocenylcorrole Cu derivative. This complex has been characterized and the preliminary electrochemical investigation shows a strong interaction among the corrole and meso ferrocenyl substituents. The results obtained suggest that peculiar properties are gained by combining the eccentric characteristics of ferrocenyl substitution with the corrole macrocycle.
ISSN:1359-7345
1364-548X
DOI:10.1039/c3cc49416k