Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS

Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS

Gold surfaces were modified by benzyl-mercaptan (BM) and then partly replaced with benzenethiol (BT), which formed binary self-assembled monolayers (SAM). Initially BT randomly replaced BM in the monolayer, but at long exchange times >15 nm radius domains were observed with specific relative comp...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-09, Vol.50 (69), p.9862-9864
Hauptverfasser: Horimoto, Noriko N, Tomizawa, Shigeru, Fujita, Yasuhiko, Kajimoto, Shinji, Fukumura, Hiroshi
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Sprache:eng
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Exchange
Gold
Monolayers
Nanostructure
Self-assembled monolayers
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container_end_page 9864
container_issue 69
container_start_page 9862
container_title Chemical communications (Cambridge, England)
container_volume 50
creator Horimoto, Noriko N
Tomizawa, Shigeru
Fujita, Yasuhiko
Kajimoto, Shinji
Fukumura, Hiroshi
description Gold surfaces were modified by benzyl-mercaptan (BM) and then partly replaced with benzenethiol (BT), which formed binary self-assembled monolayers (SAM). Initially BT randomly replaced BM in the monolayer, but at long exchange times >15 nm radius domains were observed with specific relative composition of BT and BM.
doi_str_mv 10.1039/c4cc02754j
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Exchange
Gold
Monolayers
Nanostructure
Self-assembled monolayers
title Nano-scale characterization of binary self-assembled monolayers under an ambient condition with STM and TERS
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