New ionic dinuclear Ir(III) Schiff base complexes with aggregation-induced phosphorescent emission (AIPE)

Two new ionic dinuclear Ir(III) Schiff base complexes which are straightforward to synthesise have luminescence quantum yields as high as 37% in neat films. These are the first examples of dinuclear ionic Ir(III) complexes that display aggregation-induced phosphorescent emission (AIPE).

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-07, Vol.50 (53), p.6977-6980
Hauptverfasser: Li, Guangfu, Wu, Yong, Shan, Guogang, Che, Weilong, Zhu, Dongxia, Song, Baiqiao, Yan, Likai, Su, Zhongmin, Bryce, Martin R
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container_end_page 6980
container_issue 53
container_start_page 6977
container_title Chemical communications (Cambridge, England)
container_volume 50
creator Li, Guangfu
Wu, Yong
Shan, Guogang
Che, Weilong
Zhu, Dongxia
Song, Baiqiao
Yan, Likai
Su, Zhongmin
Bryce, Martin R
description Two new ionic dinuclear Ir(III) Schiff base complexes which are straightforward to synthesise have luminescence quantum yields as high as 37% in neat films. These are the first examples of dinuclear ionic Ir(III) complexes that display aggregation-induced phosphorescent emission (AIPE).
doi_str_mv 10.1039/c4cc01799d
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source MEDLINE; Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Chelating Agents
Emission
Iridium - chemistry
Ligands
Luminescence
Luminescent Agents - chemical synthesis
Models, Molecular
Phosphorescence
Schiff bases
Schiff Bases - chemistry
Spectrometry, Mass, Electrospray Ionization
X-Ray Diffraction
title New ionic dinuclear Ir(III) Schiff base complexes with aggregation-induced phosphorescent emission (AIPE)
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