A combined stretching-tilting mechanism produces negative, zero and positive linear thermal expansion in a semi-flexible Cd(II)-MOF

A novel semi-flexible Cd(II)-MOF has been synthesized and characterized by variable temperature powder and single-crystal X-ray diffraction. The material displays an unusual combination of thermal expansion (TE) i.e. negative, zero and positive, which is an extremely rare finding, especially for met...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-06, Vol.50 (49), p.6464-6467
Hauptverfasser:	Lama, Prem, Das, Raj Kumar, Smith, Vincent J, Barbour, Leonard J
Format:	Artikel
Sprache:	eng
Schlagworte:	Displays Extreme values Metal-organic frameworks Single crystals Synthesis Thermal expansion X ray diffraction
Online-Zugang:	Volltext
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