Catalytic [3 + 2] annulation of ketimines with alkynes viaC-H activation by a cationic iridium(cod) complex

[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded viaC-H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2014-05, Vol.50 (47), p.6274-6277
Hauptverfasser:	Nagamoto, Midori, Nishimura, Takahiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Activation Alkynes Cationic Chemical reactions Derivatives Imines Organic chemistry Terminals
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creator	Nagamoto, Midori Nishimura, Takahiro
description	[3 + 2] Annulation of ketimines with internal and terminal alkynes proceeded viaC-H activation to give aminoindene derivatives in high yields, which is catalyzed by a cationic iridium complex coordinated with 1,5-cyclooctadiene (cod).
doi_str_mv	10.1039/c4cc01874e
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source	Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects	Activation Alkynes Cationic Chemical reactions Derivatives Imines Organic chemistry Terminals
title	Catalytic [3 + 2] annulation of ketimines with alkynes viaC-H activation by a cationic iridium(cod) complex
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