"114"-Type Nitrides LnAl(Si sub(4-x)Al sub(x))N sub(7)O sub( delta ) with Unusual [AlN sub(6)] Octahedral Coordination

Aluminum-nitrogen six-fold octahedral coordination, [AlN sub(6)], is unusual and has only been seen in the high-pressure rocksalt-type aluminum nitride or some complex compounds. Herein we report novel nitrides LnAl(Si sub(4-x)Al sub(x))N sub(7)O sub( delta ) (Ln=La, Sm), the first inorganic compoun...

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Veröffentlicht in:	Angewandte Chemie 2017-03, Vol.129 (14), p.3944-3949
Hauptverfasser:	Huang, Saifang, Huang, Zhaohui, Cao, Peng, Zujovic, Zoran, Price, Jason R, Avdeev, Maxim, Que, Meidan, Suzuki, Furitsu, Kido, Tsuyoshi, Ouyang, Xin, Kaji, Hironori, Fang, Minghao, Liu, Yan-gai, Gao, Wei, Sohnel, Tilo
Format:	Artikel
Sprache:	eng
Schlagworte:	Aluminum Atomic structure Complex compounds Inorganic compounds Nitrides Symmetry Synthesis X ray diffraction
Online-Zugang:	Volltext
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