Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules
The synthesis, molecular structures and luminescence properties of two 'Cu sub(12)S sub(6)' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to...
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Veröffentlicht in: | Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (75), p.11043-11045 |
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container_title | Chemical communications (Cambridge, England) |
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creator | Yang, Xiao-Xun Issac, Ibrahim Lebedkin, Sergej Kuehn, Michael Weigend, Florian Fenske, Dieter Fuhr, Olaf Eichhofer, Andreas |
description | The synthesis, molecular structures and luminescence properties of two 'Cu sub(12)S sub(6)' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to 48%) and good stability towards oxygen. |
doi_str_mv | 10.1039/c4cc04702h |
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Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to 48%) and good stability towards oxygen.</description><subject>Ambient temperature</subject><subject>Clusters</subject><subject>Ligands</subject><subject>Luminescence</subject><subject>Molecular structure</subject><subject>Optical properties</subject><subject>Phosphines</subject><subject>Stability</subject><issn>1359-7345</issn><issn>1364-548X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2014</creationdate><recordtype>article</recordtype><recordid>eNqVjrsOwjAUQyMEEs-FL8hWGAIJSWk6IxALCzCwoTZc1KD0QW-z8PUUxA_gxUeWJZuQqeALwWW8NMoYriK-yjpkIORasVDpS_fDYcwiqcI-GSI-eCsR6gE5HOHGnM9tAWigaGhqq6zEKmsDik2SWmdfcKPBxlP06Uys5qcvrOcBNc5jAzXNSwfGO8Ax6d0ThzD5-YjMdtvzZs-qunx6wOaa23bGuaSA0uNV6FhqLdq_8o_qG8SMRpU</recordid><startdate>20140801</startdate><enddate>20140801</enddate><creator>Yang, Xiao-Xun</creator><creator>Issac, Ibrahim</creator><creator>Lebedkin, Sergej</creator><creator>Kuehn, Michael</creator><creator>Weigend, Florian</creator><creator>Fenske, Dieter</creator><creator>Fuhr, Olaf</creator><creator>Eichhofer, Andreas</creator><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>L7M</scope></search><sort><creationdate>20140801</creationdate><title>Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules</title><author>Yang, Xiao-Xun ; Issac, Ibrahim ; Lebedkin, Sergej ; Kuehn, Michael ; Weigend, Florian ; Fenske, Dieter ; Fuhr, Olaf ; Eichhofer, Andreas</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-proquest_miscellaneous_18938817023</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2014</creationdate><topic>Ambient temperature</topic><topic>Clusters</topic><topic>Ligands</topic><topic>Luminescence</topic><topic>Molecular structure</topic><topic>Optical properties</topic><topic>Phosphines</topic><topic>Stability</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Yang, Xiao-Xun</creatorcontrib><creatorcontrib>Issac, Ibrahim</creatorcontrib><creatorcontrib>Lebedkin, Sergej</creatorcontrib><creatorcontrib>Kuehn, Michael</creatorcontrib><creatorcontrib>Weigend, Florian</creatorcontrib><creatorcontrib>Fenske, Dieter</creatorcontrib><creatorcontrib>Fuhr, Olaf</creatorcontrib><creatorcontrib>Eichhofer, Andreas</creatorcontrib><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Chemical communications (Cambridge, England)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Yang, Xiao-Xun</au><au>Issac, Ibrahim</au><au>Lebedkin, Sergej</au><au>Kuehn, Michael</au><au>Weigend, Florian</au><au>Fenske, Dieter</au><au>Fuhr, Olaf</au><au>Eichhofer, Andreas</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules</atitle><jtitle>Chemical communications (Cambridge, England)</jtitle><date>2014-08-01</date><risdate>2014</risdate><volume>50</volume><issue>75</issue><spage>11043</spage><epage>11045</epage><pages>11043-11045</pages><issn>1359-7345</issn><eissn>1364-548X</eissn><abstract>The synthesis, molecular structures and luminescence properties of two 'Cu sub(12)S sub(6)' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to 48%) and good stability towards oxygen.</abstract><doi>10.1039/c4cc04702h</doi></addata></record> |
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source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
subjects | Ambient temperature Clusters Ligands Luminescence Molecular structure Optical properties Phosphines Stability |
title | Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules |
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