Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules

The synthesis, molecular structures and luminescence properties of two 'Cu sub(12)S sub(6)' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to...

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Veröffentlicht in:Chemical communications (Cambridge, England) England), 2014-08, Vol.50 (75), p.11043-11045
Hauptverfasser: Yang, Xiao-Xun, Issac, Ibrahim, Lebedkin, Sergej, Kuehn, Michael, Weigend, Florian, Fenske, Dieter, Fuhr, Olaf, Eichhofer, Andreas
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container_end_page 11045
container_issue 75
container_start_page 11043
container_title Chemical communications (Cambridge, England)
container_volume 50
creator Yang, Xiao-Xun
Issac, Ibrahim
Lebedkin, Sergej
Kuehn, Michael
Weigend, Florian
Fenske, Dieter
Fuhr, Olaf
Eichhofer, Andreas
description The synthesis, molecular structures and luminescence properties of two 'Cu sub(12)S sub(6)' cluster molecules with stabilizing bidentate phosphine ligands are described. Both display in the solid state at ambient temperature high photoluminescence quantum yields ( greater than or equal to 48%) and good stability towards oxygen.
doi_str_mv 10.1039/c4cc04702h
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Ambient temperature
Clusters
Ligands
Luminescence
Molecular structure
Optical properties
Phosphines
Stability
title Red-luminescent biphosphine stabilized 'Cu sub(12)S sub(6)' cluster molecules
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