Can heterometallic 1-dimensional chains support current rectification?

To what extent can a heterometallic chain of transition metal ions generate an asymmetric current-voltage response? Density functional theory suggests that the answer depends very much on the symmetry of the dominant conduction channel: π channels are more localised and hence afford higher rectifica...

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Bibliographische Detailangaben

Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2013-01, Vol.49 (80), p.9116-9118
Hauptverfasser:	DeBrincat, Daniel, Keers, Oliver, McGrady, John E
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Channels Density functional theory Rectification Symmetry Transition metals
Online-Zugang:	Volltext
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