Catalyst-dependent intrinsic ring-walking behavior on π-face of conjugated polymers

We show that ring-walking behavior on the π-face of conjugated polymers is catalyst-dependent, and this significantly affects the composition of the products in catalyst-transfer condensation polymerization (CTCP). Systematic mechanistic study by means of density functional calculations combined wit...

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Veröffentlicht in:	Polymer chemistry 2017-03, Vol.8 (10), p.1708-1713
Hauptverfasser:	Mikami, Koichiro, Nojima, Masataka, Masumoto, Yui, Mizukoshi, Yoshihide, Takita, Ryo, Yokozawa, Tsutomu, Uchiyama, Masanobu
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysts Density Determinants Mathematical analysis Monomers Polymer chemistry Polymers Stability
Online-Zugang:	Volltext
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