Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries
Transition metal dichalcogenide materials have been considered as promising anode materials for rechargeable sodium-ion batteries because of their high specific capacity and low cost. Here, we demonstrate an iron sulfide Fe3S4 as a new anode material for a rechargeable sodium-ion battery. The involv...
Gespeichert in:
| Veröffentlicht in: | Chemical science (Cambridge) 2017-01, Vol.8 (1), p.160-164 |
|---|---|
| Hauptverfasser: | , , , , , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 164 |
|---|---|
| container_issue | 1 |
| container_start_page | 160 |
| container_title | Chemical science (Cambridge) |
| container_volume | 8 |
| creator | Li, Qidong Wei, Qiulong Zuo, Wenbin Huang, Lei Luo, Wen An, Qinyou Pelenovich, Vasiliy O Mai, Liqiang Zhang, Qingjie |
| description | Transition metal dichalcogenide materials have been considered as promising anode materials for rechargeable sodium-ion batteries because of their high specific capacity and low cost. Here, we demonstrate an iron sulfide Fe3S4 as a new anode material for a rechargeable sodium-ion battery. The involved conversion mechanism has been proved when the as-prepared Fe3S4 was used as the host material for sodium storage. Remarkably, a compound FeSx with quantum size generated by conversion reaction overcame the kinetic and thermodynamic constraints of chemical conversion to achieve superior cycling and rate capability. As a result, the as-prepared Fe3S4 electrode delivers a high reversible specific capacity of 548 mA h g-1 at 0.2 A g-1, together with an excellent cycling stability of 275 mA h g-1 after 3500 cycles at 20 A g-1. |
| doi_str_mv | 10.1039/c6sc02716d |
| format | Article |
| fullrecord | <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_miscellaneous_1893554171</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>1880026808</sourcerecordid><originalsourceid>FETCH-LOGICAL-p257t-9d28ff13b41acacd80cddb66127f092d6e937280009537cb1692143ea490c0113</originalsourceid><addsrcrecordid>eNqNjj1PwzAYhC0EElXpwi_wyGLwayf-GFFFS6VKIAFz5dhvWqMkDnEi_j5BIGZuuRse3R0h18BvgUt751X2XGhQ4YwsBC-AqVLa878s-CVZ5fzOZ0kJpdAL8rwdMB7jiHSD8qWgLlNHO_ykrksBaetGHKJraJ0GeorHE-txmHPrOo80pxCnlsXU0cqN3yTmK3JRuybj6teX5G3z8Lp-ZPun7W59v2e9KPXIbBCmrkFWBTjvfDDch1ApBULX3Iqg0EotzPzUllL7CpQVUEh0heWeA8glufnp7Yf0MWEeD23MHpvGdZimfABjZVkWoP-DzjtCGW7kF17HX3M</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880026808</pqid></control><display><type>article</type><title>Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries</title><source>DOAJ Directory of Open Access Journals</source><source>Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals</source><source>PubMed Central Open Access</source><source>PubMed Central</source><creator>Li, Qidong ; Wei, Qiulong ; Zuo, Wenbin ; Huang, Lei ; Luo, Wen ; An, Qinyou ; Pelenovich, Vasiliy O ; Mai, Liqiang ; Zhang, Qingjie</creator><creatorcontrib>Li, Qidong ; Wei, Qiulong ; Zuo, Wenbin ; Huang, Lei ; Luo, Wen ; An, Qinyou ; Pelenovich, Vasiliy O ; Mai, Liqiang ; Zhang, Qingjie</creatorcontrib><description>Transition metal dichalcogenide materials have been considered as promising anode materials for rechargeable sodium-ion batteries because of their high specific capacity and low cost. Here, we demonstrate an iron sulfide Fe3S4 as a new anode material for a rechargeable sodium-ion battery. The involved conversion mechanism has been proved when the as-prepared Fe3S4 was used as the host material for sodium storage. Remarkably, a compound FeSx with quantum size generated by conversion reaction overcame the kinetic and thermodynamic constraints of chemical conversion to achieve superior cycling and rate capability. As a result, the as-prepared Fe3S4 electrode delivers a high reversible specific capacity of 548 mA h g-1 at 0.2 A g-1, together with an excellent cycling stability of 275 mA h g-1 after 3500 cycles at 20 A g-1.</description><identifier>ISSN: 2041-6520</identifier><identifier>EISSN: 2041-6539</identifier><identifier>DOI: 10.1039/c6sc02716d</identifier><language>eng</language><subject>Anodes ; Conversion ; Cycles ; Electrodes ; Rechargeable batteries ; Sodium ; Sulfides ; Transition metals</subject><ispartof>Chemical science (Cambridge), 2017-01, Vol.8 (1), p.160-164</ispartof><lds50>peer_reviewed</lds50><oa>free_for_read</oa><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,864,27924,27925</link.rule.ids></links><search><creatorcontrib>Li, Qidong</creatorcontrib><creatorcontrib>Wei, Qiulong</creatorcontrib><creatorcontrib>Zuo, Wenbin</creatorcontrib><creatorcontrib>Huang, Lei</creatorcontrib><creatorcontrib>Luo, Wen</creatorcontrib><creatorcontrib>An, Qinyou</creatorcontrib><creatorcontrib>Pelenovich, Vasiliy O</creatorcontrib><creatorcontrib>Mai, Liqiang</creatorcontrib><creatorcontrib>Zhang, Qingjie</creatorcontrib><title>Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries</title><title>Chemical science (Cambridge)</title><description>Transition metal dichalcogenide materials have been considered as promising anode materials for rechargeable sodium-ion batteries because of their high specific capacity and low cost. Here, we demonstrate an iron sulfide Fe3S4 as a new anode material for a rechargeable sodium-ion battery. The involved conversion mechanism has been proved when the as-prepared Fe3S4 was used as the host material for sodium storage. Remarkably, a compound FeSx with quantum size generated by conversion reaction overcame the kinetic and thermodynamic constraints of chemical conversion to achieve superior cycling and rate capability. As a result, the as-prepared Fe3S4 electrode delivers a high reversible specific capacity of 548 mA h g-1 at 0.2 A g-1, together with an excellent cycling stability of 275 mA h g-1 after 3500 cycles at 20 A g-1.</description><subject>Anodes</subject><subject>Conversion</subject><subject>Cycles</subject><subject>Electrodes</subject><subject>Rechargeable batteries</subject><subject>Sodium</subject><subject>Sulfides</subject><subject>Transition metals</subject><issn>2041-6520</issn><issn>2041-6539</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNjj1PwzAYhC0EElXpwi_wyGLwayf-GFFFS6VKIAFz5dhvWqMkDnEi_j5BIGZuuRse3R0h18BvgUt751X2XGhQ4YwsBC-AqVLa878s-CVZ5fzOZ0kJpdAL8rwdMB7jiHSD8qWgLlNHO_ykrksBaetGHKJraJ0GeorHE-txmHPrOo80pxCnlsXU0cqN3yTmK3JRuybj6teX5G3z8Lp-ZPun7W59v2e9KPXIbBCmrkFWBTjvfDDch1ApBULX3Iqg0EotzPzUllL7CpQVUEh0heWeA8glufnp7Yf0MWEeD23MHpvGdZimfABjZVkWoP-DzjtCGW7kF17HX3M</recordid><startdate>20170101</startdate><enddate>20170101</enddate><creator>Li, Qidong</creator><creator>Wei, Qiulong</creator><creator>Zuo, Wenbin</creator><creator>Huang, Lei</creator><creator>Luo, Wen</creator><creator>An, Qinyou</creator><creator>Pelenovich, Vasiliy O</creator><creator>Mai, Liqiang</creator><creator>Zhang, Qingjie</creator><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>7X8</scope></search><sort><creationdate>20170101</creationdate><title>Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries</title><author>Li, Qidong ; Wei, Qiulong ; Zuo, Wenbin ; Huang, Lei ; Luo, Wen ; An, Qinyou ; Pelenovich, Vasiliy O ; Mai, Liqiang ; Zhang, Qingjie</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-p257t-9d28ff13b41acacd80cddb66127f092d6e937280009537cb1692143ea490c0113</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Anodes</topic><topic>Conversion</topic><topic>Cycles</topic><topic>Electrodes</topic><topic>Rechargeable batteries</topic><topic>Sodium</topic><topic>Sulfides</topic><topic>Transition metals</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Li, Qidong</creatorcontrib><creatorcontrib>Wei, Qiulong</creatorcontrib><creatorcontrib>Zuo, Wenbin</creatorcontrib><creatorcontrib>Huang, Lei</creatorcontrib><creatorcontrib>Luo, Wen</creatorcontrib><creatorcontrib>An, Qinyou</creatorcontrib><creatorcontrib>Pelenovich, Vasiliy O</creatorcontrib><creatorcontrib>Mai, Liqiang</creatorcontrib><creatorcontrib>Zhang, Qingjie</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>MEDLINE - Academic</collection><jtitle>Chemical science (Cambridge)</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Li, Qidong</au><au>Wei, Qiulong</au><au>Zuo, Wenbin</au><au>Huang, Lei</au><au>Luo, Wen</au><au>An, Qinyou</au><au>Pelenovich, Vasiliy O</au><au>Mai, Liqiang</au><au>Zhang, Qingjie</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries</atitle><jtitle>Chemical science (Cambridge)</jtitle><date>2017-01-01</date><risdate>2017</risdate><volume>8</volume><issue>1</issue><spage>160</spage><epage>164</epage><pages>160-164</pages><issn>2041-6520</issn><eissn>2041-6539</eissn><abstract>Transition metal dichalcogenide materials have been considered as promising anode materials for rechargeable sodium-ion batteries because of their high specific capacity and low cost. Here, we demonstrate an iron sulfide Fe3S4 as a new anode material for a rechargeable sodium-ion battery. The involved conversion mechanism has been proved when the as-prepared Fe3S4 was used as the host material for sodium storage. Remarkably, a compound FeSx with quantum size generated by conversion reaction overcame the kinetic and thermodynamic constraints of chemical conversion to achieve superior cycling and rate capability. As a result, the as-prepared Fe3S4 electrode delivers a high reversible specific capacity of 548 mA h g-1 at 0.2 A g-1, together with an excellent cycling stability of 275 mA h g-1 after 3500 cycles at 20 A g-1.</abstract><doi>10.1039/c6sc02716d</doi><tpages>5</tpages><oa>free_for_read</oa></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 2041-6520 |
| ispartof | Chemical science (Cambridge), 2017-01, Vol.8 (1), p.160-164 |
| issn | 2041-6520 2041-6539 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1893554171 |
| source | DOAJ Directory of Open Access Journals; Elektronische Zeitschriftenbibliothek - Frei zugängliche E-Journals; PubMed Central Open Access; PubMed Central |
| subjects | Anodes Conversion Cycles Electrodes Rechargeable batteries Sodium Sulfides Transition metals |
| title | Greigite Fe3S4 as a new anode material for high-performance sodium-ion batteries |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-28T18%3A24%3A08IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Greigite%20Fe3S4%20as%20a%20new%20anode%20material%20for%20high-performance%20sodium-ion%20batteries&rft.jtitle=Chemical%20science%20(Cambridge)&rft.au=Li,%20Qidong&rft.date=2017-01-01&rft.volume=8&rft.issue=1&rft.spage=160&rft.epage=164&rft.pages=160-164&rft.issn=2041-6520&rft.eissn=2041-6539&rft_id=info:doi/10.1039/c6sc02716d&rft_dat=%3Cproquest%3E1880026808%3C/proquest%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1880026808&rft_id=info:pmid/&rfr_iscdi=true |