A concerted two-prong approach to the in situ allosteric regulation of bifunctional catalysis

Herein, we report the reversible "on-off" allosteric regulation of hydrogen-bond-donating (HBD)-Lewis base co-catalytic activity a concerted two-prong methodology entailing cooperative acid-base chemistry and a structurally addressable coordination complex. Specifically, a heteroligated Pt...

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Veröffentlicht in:	Chemical science (Cambridge) 2016-11, Vol.7 (11), p.6674-6683
Hauptverfasser:	McGuirk, C Michael, Mendez-Arroyo, Jose, d'Aquino, Andrea I, Stern, Charlotte L, Liu, Yuan, Mirkin, Chad A
Format:	Artikel
Sprache:	eng
Schlagworte:	Catalysis Catalysts Catalytic activity Control Coordination compounds Ligands Polymerization Substrates
Online-Zugang:	Volltext
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