Catalytic, Enantioselective β‑Protonation through a Cooperative Activation Strategy

The NHC-catalyzed transformation of unsaturated aldehydes into saturated esters through an organocatalytic homoenolate process has been thoroughly studied. Leveraging a unique “Umpolung”-mediated β-protonation, this process has evolved from a test bed for homoenolate reactivity to a broader platform...

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Veröffentlicht in:	Journal of organic chemistry 2017-05, Vol.82 (9), p.4689-4702
Hauptverfasser:	Wang, Michael H, Barsoum, David, Schwamb, C. Benjamin, Cohen, Daniel T, Goess, Brian C, Riedrich, Matthias, Chan, Audrey, Maki, Brooks E, Mishra, Rama K, Scheidt, Karl A
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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