Induction of Axial Chirality in 8‐Arylquinolines through Halogenation Reactions Using Bifunctional Organocatalysts

The enantioselective syntheses of axially chiral heterobiaryls were accomplished through the aromatic electrophilic halogenation of 3‐(quinolin‐8‐yl)phenols with bifunctional organocatalysts that control the molecular conformations during successive halogenations. Axially chiral quinoline derivative...

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Veröffentlicht in:	Chemistry : a European journal 2017-07, Vol.23 (42), p.9996-10000
Hauptverfasser:	Miyaji, Ryota, Asano, Keisuke, Matsubara, Seijiro
Format:	Artikel
Sprache:	eng
Schlagworte:	aromatic electrophilic halogenation Asymmetric synthesis Asymmetry axial chirality bifunctional organocatalyst Bromination Catalysis Chemical synthesis Chemistry Chirality Derivatives Enantiomers Halogenation heterobiaryl Iodination Phenols Quinoline quinolines Substrates
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