Scope of the Thermal Ring‐Expansion Reaction of Boroles with Organoazides

Electronic and steric factors have been investigated in the thermal ring expansion of boroles with organic azides, a reaction that provides access to highly arylated 1,2‐azaborinines, BN analogues of benzene. Reactions of a variety of boroles and organic azides demonstrate that the synthetic method...

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Veröffentlicht in:	Chemistry : a European journal 2017-06, Vol.23 (33), p.8006-8013
Hauptverfasser:	Braunschweig, Holger, Celik, Mehmet Ali, Dellermann, Theresa, Frenking, Gernot, Hammond, Kai, Hupp, Florian, Kelch, Hauke, Krummenacher, Ivo, Lindl, Felix, Mailänder, Lisa, Müssig, Jonas H., Ruppert, Annika
Format:	Artikel
Sprache:	eng
Schlagworte:	azaborinines azides Azides (organic) Benzene boron Chemistry Electrochemistry Electronic structure Expansion heterocycles Insertion NMR Nuclear magnetic resonance ring expansion X-ray diffraction
Online-Zugang:	Volltext
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