Role of Mediator and Effects of Temperature on ortho-C–N Bond Fusion Reactions of Aniline Using Ruthenium Templates: Isolation and Characterization of New Ruthenium Complexes of the in-Situ-Generated Ligands

In this work, ortho-C–N bond fusion reactions of aniline are followed by the use of two different ruthenium mediators. Reaction of aniline with [RuIII(terpy)­Cl3] (terpy = 2,2′:6′,2″-terpyridine) resulted in a trans bis-aniline ruthenium­(II) complex [1] + which upon oxidation with H2O2 produced com...

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Veröffentlicht in:	Inorganic chemistry 2017-05, Vol.56 (9), p.4966-4977
Hauptverfasser:	Roy, Suman K, Sengupta, Debabrata, Rath, Santi Prasad, Saha, Tanushri, Samanta, Subhas, Goswami, Sreebrata
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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