The Excited-State Triple Proton Transfer Reaction of 2,6-Diazaindoles and 2,6-Diazatryptophan in Aqueous Solution

3-Me-2,6-diazaindole ((2,6-aza)­Ind) was strategically designed and synthesized to probe water molecule catalyzed excited-state proton transfer in aqueous solution. Upon electronic excitation (λmax ∼ 300 nm), (2,6-aza)­Ind undergoes N(1)–H to N(6) long-distance proton transfer in neutral H2O, result...

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Veröffentlicht in:	Journal of the American Chemical Society 2017-05, Vol.139 (18), p.6396-6402
Hauptverfasser:	Chung, Kun-You, Chen, Yi-Han, Chen, Yi-Ting, Hsu, Yen-Hao, Shen, Jiun-Yi, Chen, Chi-Lin, Chen, Yi-An, Chou, Pi-Tai
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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