Custom Coordination Environments for Lanthanoids: Tripodal Ligands Achieve Near-Perfect Octahedral Coordination for Two Dysprosium-Based Molecular Nanomagnets

Controlling the coordination sphere of lanthanoid complexes is a challenging critical step toward controlling their relaxation properties. Here we present the synthesis of hexacoordinated dysprosium single-molecule magnets, where tripodal ligands achieve a near-perfect octahedral coordination. We pe...

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Veröffentlicht in:Inorganic chemistry 2017-05, Vol.56 (9), p.4911-4917
Hauptverfasser: Lim, Kwang Soo, Baldoví, José J, Jiang, ShangDa, Koo, Bong Ho, Kang, Dong Won, Lee, Woo Ram, Koh, Eui Kwan, Gaita-Ariño, Alejandro, Coronado, Eugenio, Slota, Michael, Bogani, Lapo, Hong, Chang Seop
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Sprache:eng
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