Photolysis of a High‐Spin Azidoiron(III) Complex Studied by Time‐Resolved Fourier‐Transform Infrared Spectroscopy

The laser‐flash photolysis of the high‐spin azidoiron(III) complex [FeIII(Me3Cyclam‐ac)(N3)]PF6 ([1]PF6) in liquid acetonitrile solution at room temperature was explored by time‐resolved Fourier‐transform infrared spectroscopy. Excitation of [1] at 480 and 266 nm induced a photoreduction of the meta...

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Veröffentlicht in:	Chemistry : a European journal 2017-05, Vol.23 (28), p.6746-6751
Hauptverfasser:	Torres‐Alacan, Joel, Vöhringer, Peter
Format:	Artikel
Sprache:	eng
Schlagworte:	Acetonitrile Anions Carbon monoxide Carbonyl compounds Carbonyls Chemistry Excitation spectra Flash photolysis Fourier transforms high-valent iron Infrared lasers Infrared spectroscopy Iodides photochemistry Photolysis Photoreduction Quenching Room temperature Scavenging Spectrum analysis time-resolved transition-metal complexes
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