New Methods for the Preparation Nanosized Metal Coordination Polymers
Transition-metal coordination polymers [M(ndc)(bpy)·(H 2 O)m]·xH 2 O (where M = Co(II), Ni(II), Cu(II) and Zn(II), ndc = 1,4-naphthalenedicarboxylate, bpy = 4,4′-bipyridine; m = 0 or 1; x = 1 or 2) were prepared by reacting the ligands and metal ions at room temperature with the aid of microwave irr...
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| Veröffentlicht in: | Journal of polymers and the environment 2017-03, Vol.25 (1), p.25-34 |
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| container_title | Journal of polymers and the environment |
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| creator | Fouad, Dina M. Aly, Aref A. M. Mohammed, Mervat I. A. |
| description | Transition-metal coordination polymers [M(ndc)(bpy)·(H
2
O)m]·xH
2
O (where M = Co(II), Ni(II), Cu(II) and Zn(II), ndc = 1,4-naphthalenedicarboxylate, bpy = 4,4′-bipyridine; m = 0 or 1; x = 1 or 2) were prepared by reacting the ligands and metal ions at room temperature with the aid of microwave irradiation and sonication methods. The structure of the coordination polymers was assigned based on elemental analysis, FT-IR and electronic spectral studies, thermal analysis, scanning electron microscope and X-ray powder diffraction. Thermogravimetric analysis was also used to follow up the possible thermal decomposition steps and to calculate the thermodynamic parameters of the nano-sized metal complexes. The kinetic parameters were calculated making use of the Coats–Redfern and Horowitz–Metzger equations. All obtained results of the different technics used in our study stated the ability to synthesis the metal coordination polymers of our interest using both microwave irradiation and sonication methods. |
| doi_str_mv | 10.1007/s10924-016-0781-8 |
| format | Article |
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2
O)m]·xH
2
O (where M = Co(II), Ni(II), Cu(II) and Zn(II), ndc = 1,4-naphthalenedicarboxylate, bpy = 4,4′-bipyridine; m = 0 or 1; x = 1 or 2) were prepared by reacting the ligands and metal ions at room temperature with the aid of microwave irradiation and sonication methods. The structure of the coordination polymers was assigned based on elemental analysis, FT-IR and electronic spectral studies, thermal analysis, scanning electron microscope and X-ray powder diffraction. Thermogravimetric analysis was also used to follow up the possible thermal decomposition steps and to calculate the thermodynamic parameters of the nano-sized metal complexes. The kinetic parameters were calculated making use of the Coats–Redfern and Horowitz–Metzger equations. All obtained results of the different technics used in our study stated the ability to synthesis the metal coordination polymers of our interest using both microwave irradiation and sonication methods.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>EISSN: 1572-8900</identifier><identifier>DOI: 10.1007/s10924-016-0781-8</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Coordination polymers ; Electronics ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Industrial Chemistry/Chemical Engineering ; Irradiation ; Materials Science ; Mathematical analysis ; Metal complexes ; Metals ; Microwaves ; Nanomaterials ; Nanostructure ; Nickel ; Original Paper ; Parameters ; Polymer Sciences ; Polymers ; Scanning electron microscopy ; Thermal analysis ; Thermal decomposition</subject><ispartof>Journal of polymers and the environment, 2017-03, Vol.25 (1), p.25-34</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Journal of Polymers and the Environment is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c386t-d6df1c550301d09c8fbec7c9fd5b4d043161a4bc14f379f8b89f083c947bf1d3</citedby><cites>FETCH-LOGICAL-c386t-d6df1c550301d09c8fbec7c9fd5b4d043161a4bc14f379f8b89f083c947bf1d3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-016-0781-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-016-0781-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Fouad, Dina M.</creatorcontrib><creatorcontrib>Aly, Aref A. M.</creatorcontrib><creatorcontrib>Mohammed, Mervat I. A.</creatorcontrib><title>New Methods for the Preparation Nanosized Metal Coordination Polymers</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>Transition-metal coordination polymers [M(ndc)(bpy)·(H
2
O)m]·xH
2
O (where M = Co(II), Ni(II), Cu(II) and Zn(II), ndc = 1,4-naphthalenedicarboxylate, bpy = 4,4′-bipyridine; m = 0 or 1; x = 1 or 2) were prepared by reacting the ligands and metal ions at room temperature with the aid of microwave irradiation and sonication methods. The structure of the coordination polymers was assigned based on elemental analysis, FT-IR and electronic spectral studies, thermal analysis, scanning electron microscope and X-ray powder diffraction. Thermogravimetric analysis was also used to follow up the possible thermal decomposition steps and to calculate the thermodynamic parameters of the nano-sized metal complexes. The kinetic parameters were calculated making use of the Coats–Redfern and Horowitz–Metzger equations. All obtained results of the different technics used in our study stated the ability to synthesis the metal coordination polymers of our interest using both microwave irradiation and sonication methods.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Coordination polymers</subject><subject>Electronics</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Irradiation</subject><subject>Materials Science</subject><subject>Mathematical analysis</subject><subject>Metal complexes</subject><subject>Metals</subject><subject>Microwaves</subject><subject>Nanomaterials</subject><subject>Nanostructure</subject><subject>Nickel</subject><subject>Original Paper</subject><subject>Parameters</subject><subject>Polymer Sciences</subject><subject>Polymers</subject><subject>Scanning electron microscopy</subject><subject>Thermal analysis</subject><subject>Thermal decomposition</subject><issn>1566-2543</issn><issn>1572-8919</issn><issn>1572-8900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kE1Lw0AQhoMoWKs_wFvAi5fVmWSz2T1KqR9Qaw-9L5v9sClptu6miP56E-NBBE8zMM_7MjxJcolwgwDlbUQQGSWAjEDJkfCjZIJFmREuUBwPO2MkK2h-mpzFuAUA0ecmyXxp39Nn2228ianzIe02Nl0Fu1dBdbVv06Vqfaw_rRko1aQz74Op2_G48s3HzoZ4npw41UR78TOnyfp-vp49ksXLw9PsbkF0zllHDDMOdVFADmhAaO4qq0stnCkqaoDmyFDRSiN1eSkcr7hwwHMtaFk5NPk0uR5r98G_HWzs5K6O2jaNaq0_RImcU8SSIevRqz_o1h9C2z_XU0xAxvGbwpHSwccYrJP7UO9U-JAIcvAqR6-y9yoHr5L3mWzMxJ5tX2341fxv6AsL5Xo4</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Fouad, Dina M.</creator><creator>Aly, Aref A. 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A.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c386t-d6df1c550301d09c8fbec7c9fd5b4d043161a4bc14f379f8b89f083c947bf1d3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Coordination polymers</topic><topic>Electronics</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Irradiation</topic><topic>Materials Science</topic><topic>Mathematical analysis</topic><topic>Metal complexes</topic><topic>Metals</topic><topic>Microwaves</topic><topic>Nanomaterials</topic><topic>Nanostructure</topic><topic>Nickel</topic><topic>Original Paper</topic><topic>Parameters</topic><topic>Polymer Sciences</topic><topic>Polymers</topic><topic>Scanning electron microscopy</topic><topic>Thermal analysis</topic><topic>Thermal decomposition</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Fouad, Dina M.</creatorcontrib><creatorcontrib>Aly, Aref A. M.</creatorcontrib><creatorcontrib>Mohammed, Mervat I. 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M.</au><au>Mohammed, Mervat I. A.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>New Methods for the Preparation Nanosized Metal Coordination Polymers</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>25</volume><issue>1</issue><spage>25</spage><epage>34</epage><pages>25-34</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><eissn>1572-8900</eissn><abstract>Transition-metal coordination polymers [M(ndc)(bpy)·(H
2
O)m]·xH
2
O (where M = Co(II), Ni(II), Cu(II) and Zn(II), ndc = 1,4-naphthalenedicarboxylate, bpy = 4,4′-bipyridine; m = 0 or 1; x = 1 or 2) were prepared by reacting the ligands and metal ions at room temperature with the aid of microwave irradiation and sonication methods. The structure of the coordination polymers was assigned based on elemental analysis, FT-IR and electronic spectral studies, thermal analysis, scanning electron microscope and X-ray powder diffraction. Thermogravimetric analysis was also used to follow up the possible thermal decomposition steps and to calculate the thermodynamic parameters of the nano-sized metal complexes. The kinetic parameters were calculated making use of the Coats–Redfern and Horowitz–Metzger equations. All obtained results of the different technics used in our study stated the ability to synthesis the metal coordination polymers of our interest using both microwave irradiation and sonication methods.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-016-0781-8</doi><tpages>10</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Coordination polymers Electronics Environmental Chemistry Environmental Engineering/Biotechnology Industrial Chemistry/Chemical Engineering Irradiation Materials Science Mathematical analysis Metal complexes Metals Microwaves Nanomaterials Nanostructure Nickel Original Paper Parameters Polymer Sciences Polymers Scanning electron microscopy Thermal analysis Thermal decomposition |
| title | New Methods for the Preparation Nanosized Metal Coordination Polymers |
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