Some Investigations on the Nylon 6/Zn Composite Material Obtained by Simultaneous Anionic Polymerization-Molding Process
This study is concerned with the behavior of samples based on nylon 6/zinc (Ny6/Zn) composite material in high salinity water that contains NaCl (3.5 wt%) and in aqueous solution of HCl (0.5 N and 1 N). The samples were obtained from parts prepared by in situ anionic ring-opening polymerization of є...
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| Veröffentlicht in: | Journal of polymers and the environment 2017-03, Vol.25 (1), p.11-24 |
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| creator | Rusu, Elena Rusu, Gheorghe |
| description | This study is concerned with the behavior of samples based on nylon 6/zinc (Ny6/Zn) composite material in high salinity water that contains NaCl (3.5 wt%) and in aqueous solution of HCl (0.5 N and 1 N). The samples were obtained from parts prepared by in situ anionic ring-opening polymerization of є-caprolactam (CL) in the presence of zinc (Zn), as filler (15 wt%) using the rotational molding technique. This type of composite was evaluated by the testing of swelling degree, structural modifications, evolution of hydrogen and electrochemical behavior. The properties of Ny6/Zn composite material have ascertained through the combined use of more analysis methods: attenuated total reflectance Fourier transform infrared spectroscopy, wide-angle X-ray diffraction technique, scanning electron microscopy, swelling and electrochemical measurements. It was revealed that regarding swelling behavior the Ny6 matrix has an important role while Zn filler contributes especially to the (electro)chemical corrosion. |
| doi_str_mv | 10.1007/s10924-016-0779-2 |
| format | Article |
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The samples were obtained from parts prepared by in situ anionic ring-opening polymerization of є-caprolactam (CL) in the presence of zinc (Zn), as filler (15 wt%) using the rotational molding technique. This type of composite was evaluated by the testing of swelling degree, structural modifications, evolution of hydrogen and electrochemical behavior. The properties of Ny6/Zn composite material have ascertained through the combined use of more analysis methods: attenuated total reflectance Fourier transform infrared spectroscopy, wide-angle X-ray diffraction technique, scanning electron microscopy, swelling and electrochemical measurements. It was revealed that regarding swelling behavior the Ny6 matrix has an important role while Zn filler contributes especially to the (electro)chemical corrosion.</description><identifier>ISSN: 1566-2543</identifier><identifier>EISSN: 1572-8919</identifier><identifier>EISSN: 1572-8900</identifier><identifier>DOI: 10.1007/s10924-016-0779-2</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Chemistry ; Chemistry and Materials Science ; Composite materials ; Electrochemistry ; Environmental Chemistry ; Environmental Engineering/Biotechnology ; Fillers ; Fourier transforms ; Industrial Chemistry/Chemical Engineering ; Infrared spectroscopy ; Materials Science ; Molds & molding ; Nylon ; Nylon 6 ; Original Paper ; Polymer matrix composites ; Polymer Sciences ; Polymerization ; Rotational molding ; Sodium chloride ; Swelling ; X-ray diffraction ; Zinc</subject><ispartof>Journal of polymers and the environment, 2017-03, Vol.25 (1), p.11-24</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>Journal of Polymers and the Environment is a copyright of Springer, 2017.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c349t-696d8ed8bb61532b4b631c4cd265827f3360046cba046864099ece5bcca940163</citedby><cites>FETCH-LOGICAL-c349t-696d8ed8bb61532b4b631c4cd265827f3360046cba046864099ece5bcca940163</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s10924-016-0779-2$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s10924-016-0779-2$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,780,784,27924,27925,41488,42557,51319</link.rule.ids></links><search><creatorcontrib>Rusu, Elena</creatorcontrib><creatorcontrib>Rusu, Gheorghe</creatorcontrib><title>Some Investigations on the Nylon 6/Zn Composite Material Obtained by Simultaneous Anionic Polymerization-Molding Process</title><title>Journal of polymers and the environment</title><addtitle>J Polym Environ</addtitle><description>This study is concerned with the behavior of samples based on nylon 6/zinc (Ny6/Zn) composite material in high salinity water that contains NaCl (3.5 wt%) and in aqueous solution of HCl (0.5 N and 1 N). The samples were obtained from parts prepared by in situ anionic ring-opening polymerization of є-caprolactam (CL) in the presence of zinc (Zn), as filler (15 wt%) using the rotational molding technique. This type of composite was evaluated by the testing of swelling degree, structural modifications, evolution of hydrogen and electrochemical behavior. The properties of Ny6/Zn composite material have ascertained through the combined use of more analysis methods: attenuated total reflectance Fourier transform infrared spectroscopy, wide-angle X-ray diffraction technique, scanning electron microscopy, swelling and electrochemical measurements. It was revealed that regarding swelling behavior the Ny6 matrix has an important role while Zn filler contributes especially to the (electro)chemical corrosion.</description><subject>Chemistry</subject><subject>Chemistry and Materials Science</subject><subject>Composite materials</subject><subject>Electrochemistry</subject><subject>Environmental Chemistry</subject><subject>Environmental Engineering/Biotechnology</subject><subject>Fillers</subject><subject>Fourier transforms</subject><subject>Industrial Chemistry/Chemical Engineering</subject><subject>Infrared spectroscopy</subject><subject>Materials Science</subject><subject>Molds & molding</subject><subject>Nylon</subject><subject>Nylon 6</subject><subject>Original Paper</subject><subject>Polymer matrix composites</subject><subject>Polymer Sciences</subject><subject>Polymerization</subject><subject>Rotational molding</subject><subject>Sodium chloride</subject><subject>Swelling</subject><subject>X-ray diffraction</subject><subject>Zinc</subject><issn>1566-2543</issn><issn>1572-8919</issn><issn>1572-8900</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><sourceid>ABUWG</sourceid><sourceid>AFKRA</sourceid><sourceid>AZQEC</sourceid><sourceid>BENPR</sourceid><sourceid>CCPQU</sourceid><sourceid>DWQXO</sourceid><sourceid>GNUQQ</sourceid><recordid>eNp1kU9PAyEQxTdGE2v1A3gj8eIFCyzLwtE0_mnSapPqxQthWVppdqHC1lg_vdT1YEy8MHP4vcfMvCw7x-gKI1SOIkaCUIgwg6gsBSQH2QAXJYFcYHG47xmDpKD5cXYS4xohJJJukH0sfGvAxL2b2NmV6qx3EXgHulcDHnZN6tjoxYGxbzc-2s6AmepMsKoBj1WnrDM1qHZgYdtt0yln_DaCa5dMrAZz3-zaxH5-u8KZb2rrVmAevDYxnmZHS9VEc_ZTh9nz7c3T-B5OH-8m4-sp1DkVHWSC1dzUvKoYLnJS0YrlWFNdE1ZwUi7znCFEma5UejmjSAijTVFprQRN18iH2WXvuwn-bZu2lK2N2jRNP63EnFOMS8p5Qi_-oGu_DS5NlygmEBG4LBOFe0oHH2MwS7kJtlVhJzGS-yxkn4VMv8t9FpIkDek1MbFuZcIv539FX7ikjJw</recordid><startdate>20170301</startdate><enddate>20170301</enddate><creator>Rusu, Elena</creator><creator>Rusu, Gheorghe</creator><general>Springer US</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>3V.</scope><scope>7SR</scope><scope>7XB</scope><scope>88I</scope><scope>8AO</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>8FK</scope><scope>ABJCF</scope><scope>ABUWG</scope><scope>AFKRA</scope><scope>ATCPS</scope><scope>AZQEC</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>BHPHI</scope><scope>BKSAR</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>GNUQQ</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>M2P</scope><scope>PATMY</scope><scope>PCBAR</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PYCSY</scope><scope>Q9U</scope><scope>7SE</scope></search><sort><creationdate>20170301</creationdate><title>Some Investigations on the Nylon 6/Zn Composite Material Obtained by Simultaneous Anionic Polymerization-Molding Process</title><author>Rusu, Elena ; Rusu, Gheorghe</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c349t-696d8ed8bb61532b4b631c4cd265827f3360046cba046864099ece5bcca940163</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Chemistry</topic><topic>Chemistry and Materials Science</topic><topic>Composite materials</topic><topic>Electrochemistry</topic><topic>Environmental Chemistry</topic><topic>Environmental Engineering/Biotechnology</topic><topic>Fillers</topic><topic>Fourier transforms</topic><topic>Industrial Chemistry/Chemical Engineering</topic><topic>Infrared spectroscopy</topic><topic>Materials Science</topic><topic>Molds & molding</topic><topic>Nylon</topic><topic>Nylon 6</topic><topic>Original Paper</topic><topic>Polymer matrix composites</topic><topic>Polymer Sciences</topic><topic>Polymerization</topic><topic>Rotational molding</topic><topic>Sodium chloride</topic><topic>Swelling</topic><topic>X-ray diffraction</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Rusu, Elena</creatorcontrib><creatorcontrib>Rusu, Gheorghe</creatorcontrib><collection>CrossRef</collection><collection>ProQuest Central (Corporate)</collection><collection>Engineered Materials Abstracts</collection><collection>ProQuest Central (purchase pre-March 2016)</collection><collection>Science Database (Alumni Edition)</collection><collection>ProQuest Pharma Collection</collection><collection>Technology Research Database</collection><collection>ProQuest SciTech Collection</collection><collection>ProQuest Technology Collection</collection><collection>ProQuest Central (Alumni) (purchase pre-March 2016)</collection><collection>Materials Science & Engineering Collection</collection><collection>ProQuest Central (Alumni Edition)</collection><collection>ProQuest Central UK/Ireland</collection><collection>Agricultural & Environmental Science Collection</collection><collection>ProQuest Central Essentials</collection><collection>ProQuest Central</collection><collection>Technology Collection</collection><collection>Natural Science Collection</collection><collection>Earth, Atmospheric & Aquatic Science Collection</collection><collection>ProQuest One Community College</collection><collection>ProQuest Materials Science Collection</collection><collection>ProQuest Central Korea</collection><collection>ProQuest Central Student</collection><collection>SciTech Premium Collection</collection><collection>Materials Research Database</collection><collection>Materials Science Database</collection><collection>Science Database</collection><collection>Environmental Science Database</collection><collection>Earth, Atmospheric & Aquatic Science Database</collection><collection>Materials Science Collection</collection><collection>ProQuest One Academic Eastern Edition (DO NOT USE)</collection><collection>ProQuest One Academic</collection><collection>ProQuest One Academic UKI Edition</collection><collection>Environmental Science Collection</collection><collection>ProQuest Central Basic</collection><collection>Corrosion Abstracts</collection><jtitle>Journal of polymers and the environment</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Rusu, Elena</au><au>Rusu, Gheorghe</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Some Investigations on the Nylon 6/Zn Composite Material Obtained by Simultaneous Anionic Polymerization-Molding Process</atitle><jtitle>Journal of polymers and the environment</jtitle><stitle>J Polym Environ</stitle><date>2017-03-01</date><risdate>2017</risdate><volume>25</volume><issue>1</issue><spage>11</spage><epage>24</epage><pages>11-24</pages><issn>1566-2543</issn><eissn>1572-8919</eissn><eissn>1572-8900</eissn><abstract>This study is concerned with the behavior of samples based on nylon 6/zinc (Ny6/Zn) composite material in high salinity water that contains NaCl (3.5 wt%) and in aqueous solution of HCl (0.5 N and 1 N). The samples were obtained from parts prepared by in situ anionic ring-opening polymerization of є-caprolactam (CL) in the presence of zinc (Zn), as filler (15 wt%) using the rotational molding technique. This type of composite was evaluated by the testing of swelling degree, structural modifications, evolution of hydrogen and electrochemical behavior. The properties of Ny6/Zn composite material have ascertained through the combined use of more analysis methods: attenuated total reflectance Fourier transform infrared spectroscopy, wide-angle X-ray diffraction technique, scanning electron microscopy, swelling and electrochemical measurements. It was revealed that regarding swelling behavior the Ny6 matrix has an important role while Zn filler contributes especially to the (electro)chemical corrosion.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s10924-016-0779-2</doi><tpages>14</tpages></addata></record> |
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| subjects | Chemistry Chemistry and Materials Science Composite materials Electrochemistry Environmental Chemistry Environmental Engineering/Biotechnology Fillers Fourier transforms Industrial Chemistry/Chemical Engineering Infrared spectroscopy Materials Science Molds & molding Nylon Nylon 6 Original Paper Polymer matrix composites Polymer Sciences Polymerization Rotational molding Sodium chloride Swelling X-ray diffraction Zinc |
| title | Some Investigations on the Nylon 6/Zn Composite Material Obtained by Simultaneous Anionic Polymerization-Molding Process |
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