Evaluation of physical, rheological, and structural properties of vulcanized EVA/SBS modified bitumen

ABSTRACT In this study, the performance and modification mechanism of EVA (ethylene‐vinyl‐acetate) modified (EM), EVA/SBS (Styrene‐Butadiene‐Styrene) modified (ESM), and EVA/SBS/sulfur modified (ESSM) bitumens were evaluated. The physical, rheological, morphological, and structural properties were d...

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Veröffentlicht in:Journal of applied polymer science 2017-06, Vol.134 (21), p.np-n/a
Hauptverfasser: Jiang, Zhenliang, Hu, Changbin, Easa, Said M., Zheng, Xiaoyan, Zhang, Yu
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container_issue 21
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container_title Journal of applied polymer science
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creator Jiang, Zhenliang
Hu, Changbin
Easa, Said M.
Zheng, Xiaoyan
Zhang, Yu
description ABSTRACT In this study, the performance and modification mechanism of EVA (ethylene‐vinyl‐acetate) modified (EM), EVA/SBS (Styrene‐Butadiene‐Styrene) modified (ESM), and EVA/SBS/sulfur modified (ESSM) bitumens were evaluated. The physical, rheological, morphological, and structural properties were determined before and after aging, and compared with those of base bitumen. These properties were evaluation using conventional physical methods, Fourier transform infrared spectrometer, optical microscopy, dynamic shear rheometer, and bending beam rheometer, respectively. The results showed that sulfur was useful in bitumen, EVA, and SBS modification by forming a vulcanized crosslinking polymer network. The vulcanization improved most of the physical properties of ESM bitumen, especially high‐ and low‐temperature performance, and toughness and tenacity (previously not evaluated in the literature). Meanwhile, vulcanization improved the compatibility between polymers and bitumen and increased the aging resistance of ESM bitumen. Vulcanization reactions took place without new functional groups being presented in the infrared spectrum. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44850.
doi_str_mv 10.1002/app.44850
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The physical, rheological, morphological, and structural properties were determined before and after aging, and compared with those of base bitumen. These properties were evaluation using conventional physical methods, Fourier transform infrared spectrometer, optical microscopy, dynamic shear rheometer, and bending beam rheometer, respectively. The results showed that sulfur was useful in bitumen, EVA, and SBS modification by forming a vulcanized crosslinking polymer network. The vulcanization improved most of the physical properties of ESM bitumen, especially high‐ and low‐temperature performance, and toughness and tenacity (previously not evaluated in the literature). Meanwhile, vulcanization improved the compatibility between polymers and bitumen and increased the aging resistance of ESM bitumen. Vulcanization reactions took place without new functional groups being presented in the infrared spectrum. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. 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The physical, rheological, morphological, and structural properties were determined before and after aging, and compared with those of base bitumen. These properties were evaluation using conventional physical methods, Fourier transform infrared spectrometer, optical microscopy, dynamic shear rheometer, and bending beam rheometer, respectively. The results showed that sulfur was useful in bitumen, EVA, and SBS modification by forming a vulcanized crosslinking polymer network. The vulcanization improved most of the physical properties of ESM bitumen, especially high‐ and low‐temperature performance, and toughness and tenacity (previously not evaluated in the literature). Meanwhile, vulcanization improved the compatibility between polymers and bitumen and increased the aging resistance of ESM bitumen. Vulcanization reactions took place without new functional groups being presented in the infrared spectrum. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017, 134, 44850.</abstract><cop>Hoboken</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/app.44850</doi><tpages>10</tpages></addata></record>
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source Wiley Online Library Journals Frontfile Complete
subjects Beams (radiation)
Bitumens
Ethylene vinyl acetates
EVA
Materials science
physical
Polymers
rheological
Rheological properties
Rheometers
SBS
structural
Sulfur
Vulcanization
vulcanize
Vulcanizing
title Evaluation of physical, rheological, and structural properties of vulcanized EVA/SBS modified bitumen
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