Free‐Radical Carbo‐Alkenylation of Olefins: Scope, Limitations and Mechanistic Insights

The three‐component free‐radical carbo‐alkenylation of electron‐rich olefins has been studied, varying the substitution pattern in the alkene, in the radical precursor and in the final acceptor. New vinylsulfones were also prepared and their reactivity investigated. The scope and limitations of the...

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Veröffentlicht in:	Chemistry : a European journal 2017-02, Vol.23 (10), p.2439-2447
Hauptverfasser:	Beniazza, Redouane, Liautard, Virginie, Poittevin, Clément, Ovadia, Benjamin, Mohammed, Shireen, Robert, Frédéric, Landais, Yannick
Format:	Artikel
Sprache:	eng
Schlagworte:	addition–elimination Chemistry Clocks Dienes Free radicals multicomponent reactions Olefins Precursors Radicals Reaction mechanisms β-fragmentation
Online-Zugang:	Volltext
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