Electrodes Based on Amorphous Metallic Aluminum Alloys in the Reactions of Hydrogen Release
We estimate the electrochemical activity of specimens of the amorphous metallic alloys (АМA) Al 87 Ni 8 Y 5 , Al 87 Ni 8 Y 4 Gd 1 , and Al 87 Ni 8 Dy 1 Y 4 in alkaline solutions of potassium hydroxide of different concentrations and the influence of partial substitution of 1 at. % Gd or Dy for Y. It...
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| Veröffentlicht in: | Materials science (New York, N.Y.) N.Y.), 2016, Vol.51 (4), p.548-554 |
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| creator | Boichyshyn, L. М. Hertsyk, О. М. Kovbuz, М. О. Kotur, B. Ya Nosenko, V. K. |
| description | We estimate the electrochemical activity of specimens of the amorphous metallic alloys (АМA) Al
87
Ni
8
Y
5
, Al
87
Ni
8
Y
4
Gd
1
, and Al
87
Ni
8
Dy
1
Y
4
in alkaline solutions of potassium hydroxide of different concentrations and the influence of partial substitution of 1 at. % Gd or Dy for Y. It is shown that all investigated specimens are corrosion-resistant in the course of cyclic polarization within the potential range from – 1.2 to + 1.0 V in aqueous KОН solutions of various concentrations (0.5–5.0) М. It is shown that AMA electrodes alloyed with 1 at.% Dy exhibit the highest catalytic activity in a 4 М KОН solution. |
| doi_str_mv | 10.1007/s11003-016-9874-8 |
| format | Article |
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87
Ni
8
Y
5
, Al
87
Ni
8
Y
4
Gd
1
, and Al
87
Ni
8
Dy
1
Y
4
in alkaline solutions of potassium hydroxide of different concentrations and the influence of partial substitution of 1 at. % Gd or Dy for Y. It is shown that all investigated specimens are corrosion-resistant in the course of cyclic polarization within the potential range from – 1.2 to + 1.0 V in aqueous KОН solutions of various concentrations (0.5–5.0) М. It is shown that AMA electrodes alloyed with 1 at.% Dy exhibit the highest catalytic activity in a 4 М KОН solution.</description><identifier>ISSN: 1068-820X</identifier><identifier>EISSN: 1573-885X</identifier><identifier>DOI: 10.1007/s11003-016-9874-8</identifier><identifier>CODEN: MSCIEQ</identifier><language>eng</language><publisher>New York: Springer US</publisher><subject>Aluminum ; Aluminum alloys ; Aluminum base alloys ; Catalytic activity ; Characterization and Evaluation of Materials ; Chemistry and Materials Science ; Corrosion and anti-corrosives ; Corrosion resistance ; Electrodes ; Electrolytes ; Estimates ; Hydrogen ; Hydroxides ; Materials Science ; Medical societies ; Polarization ; Potassium hydroxides ; Solid Mechanics ; Structural Materials</subject><ispartof>Materials science (New York, N.Y.), 2016, Vol.51 (4), p.548-554</ispartof><rights>Springer Science+Business Media New York 2016</rights><rights>COPYRIGHT 2016 Springer</rights><rights>Materials Science is a copyright of Springer, 2016.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c422t-743d60645f300b9b2906eb789381d5382f39543c6356773d066dc26a4f04eb43</citedby><cites>FETCH-LOGICAL-c422t-743d60645f300b9b2906eb789381d5382f39543c6356773d066dc26a4f04eb43</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktopdf>$$Uhttps://link.springer.com/content/pdf/10.1007/s11003-016-9874-8$$EPDF$$P50$$Gspringer$$H</linktopdf><linktohtml>$$Uhttps://link.springer.com/10.1007/s11003-016-9874-8$$EHTML$$P50$$Gspringer$$H</linktohtml><link.rule.ids>314,776,780,27901,27902,41464,42533,51294</link.rule.ids></links><search><creatorcontrib>Boichyshyn, L. М.</creatorcontrib><creatorcontrib>Hertsyk, О. М.</creatorcontrib><creatorcontrib>Kovbuz, М. О.</creatorcontrib><creatorcontrib>Kotur, B. Ya</creatorcontrib><creatorcontrib>Nosenko, V. K.</creatorcontrib><title>Electrodes Based on Amorphous Metallic Aluminum Alloys in the Reactions of Hydrogen Release</title><title>Materials science (New York, N.Y.)</title><addtitle>Mater Sci</addtitle><description>We estimate the electrochemical activity of specimens of the amorphous metallic alloys (АМA) Al
87
Ni
8
Y
5
, Al
87
Ni
8
Y
4
Gd
1
, and Al
87
Ni
8
Dy
1
Y
4
in alkaline solutions of potassium hydroxide of different concentrations and the influence of partial substitution of 1 at. % Gd or Dy for Y. It is shown that all investigated specimens are corrosion-resistant in the course of cyclic polarization within the potential range from – 1.2 to + 1.0 V in aqueous KОН solutions of various concentrations (0.5–5.0) М. It is shown that AMA electrodes alloyed with 1 at.% Dy exhibit the highest catalytic activity in a 4 М KОН solution.</description><subject>Aluminum</subject><subject>Aluminum alloys</subject><subject>Aluminum base alloys</subject><subject>Catalytic activity</subject><subject>Characterization and Evaluation of Materials</subject><subject>Chemistry and Materials Science</subject><subject>Corrosion and anti-corrosives</subject><subject>Corrosion resistance</subject><subject>Electrodes</subject><subject>Electrolytes</subject><subject>Estimates</subject><subject>Hydrogen</subject><subject>Hydroxides</subject><subject>Materials Science</subject><subject>Medical societies</subject><subject>Polarization</subject><subject>Potassium hydroxides</subject><subject>Solid Mechanics</subject><subject>Structural Materials</subject><issn>1068-820X</issn><issn>1573-885X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><sourceid>BENPR</sourceid><recordid>eNp1kU9LHTEUxYfSglb7AdwFumkXo_k_meWrWBUUwboQugh5mTvPSCZ5TTLQ9-3NY7pQodzFvVx-53Iup2lOCD4lGHdnmdTGWkxk26uOt-pDc0hEx1qlxOPHOmOpWkXx40HzOednXDWiE4fN7wsPtqQ4QEY_TIYBxYBWU0zbpzhndAvFeO8sWvl5cmGe6uDjLiMXUHkCdA_GFhdDRnFEV7shxQ2EuvVQbx03n0bjM3z514-ah58XD-dX7c3d5fX56qa1nNLSdpwNEksuRobxul_THktYd6pnigyCKTqyXnBmJROy69iApRwslYaPmMOas6Pm23J2m-KfGXLRk8sWvDcB6g-aKMUJVrTfo1_foc9xTqGaq5QUDAtKVaVOF2pjPGgXxliSsbUGmJyNAUZX9ysuCBWKir4Kvr8RVKbA37Ixc876-tf9W5YsrE0x5wSj3iY3mbTTBOt9lHqJUtco9T5KvTdEF02ubNhAemX7v6IXIn6d4w</recordid><startdate>2016</startdate><enddate>2016</enddate><creator>Boichyshyn, L. М.</creator><creator>Hertsyk, О. М.</creator><creator>Kovbuz, М. О.</creator><creator>Kotur, B. Ya</creator><creator>Nosenko, V. K.</creator><general>Springer US</general><general>Springer</general><general>Springer Nature B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>ISR</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>8FE</scope><scope>8FG</scope><scope>ABJCF</scope><scope>AFKRA</scope><scope>BENPR</scope><scope>BGLVJ</scope><scope>CCPQU</scope><scope>D1I</scope><scope>DWQXO</scope><scope>HCIFZ</scope><scope>JG9</scope><scope>KB.</scope><scope>PDBOC</scope><scope>PQEST</scope><scope>PQQKQ</scope><scope>PQUKI</scope><scope>PRINS</scope><scope>7QF</scope><scope>7SE</scope></search><sort><creationdate>2016</creationdate><title>Electrodes Based on Amorphous Metallic Aluminum Alloys in the Reactions of Hydrogen Release</title><author>Boichyshyn, L. М. ; Hertsyk, О. М. ; Kovbuz, М. О. ; Kotur, B. Ya ; Nosenko, V. K.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c422t-743d60645f300b9b2906eb789381d5382f39543c6356773d066dc26a4f04eb43</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Aluminum</topic><topic>Aluminum alloys</topic><topic>Aluminum base alloys</topic><topic>Catalytic activity</topic><topic>Characterization and Evaluation of Materials</topic><topic>Chemistry and Materials Science</topic><topic>Corrosion and anti-corrosives</topic><topic>Corrosion resistance</topic><topic>Electrodes</topic><topic>Electrolytes</topic><topic>Estimates</topic><topic>Hydrogen</topic><topic>Hydroxides</topic><topic>Materials Science</topic><topic>Medical societies</topic><topic>Polarization</topic><topic>Potassium hydroxides</topic><topic>Solid Mechanics</topic><topic>Structural Materials</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Boichyshyn, L. М.</creatorcontrib><creatorcontrib>Hertsyk, О. М.</creatorcontrib><creatorcontrib>Kovbuz, М. О.</creatorcontrib><creatorcontrib>Kotur, B. Ya</creatorcontrib><creatorcontrib>Nosenko, V. 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М.</au><au>Hertsyk, О. М.</au><au>Kovbuz, М. О.</au><au>Kotur, B. Ya</au><au>Nosenko, V. K.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Electrodes Based on Amorphous Metallic Aluminum Alloys in the Reactions of Hydrogen Release</atitle><jtitle>Materials science (New York, N.Y.)</jtitle><stitle>Mater Sci</stitle><date>2016</date><risdate>2016</risdate><volume>51</volume><issue>4</issue><spage>548</spage><epage>554</epage><pages>548-554</pages><issn>1068-820X</issn><eissn>1573-885X</eissn><coden>MSCIEQ</coden><abstract>We estimate the electrochemical activity of specimens of the amorphous metallic alloys (АМA) Al
87
Ni
8
Y
5
, Al
87
Ni
8
Y
4
Gd
1
, and Al
87
Ni
8
Dy
1
Y
4
in alkaline solutions of potassium hydroxide of different concentrations and the influence of partial substitution of 1 at. % Gd or Dy for Y. It is shown that all investigated specimens are corrosion-resistant in the course of cyclic polarization within the potential range from – 1.2 to + 1.0 V in aqueous KОН solutions of various concentrations (0.5–5.0) М. It is shown that AMA electrodes alloyed with 1 at.% Dy exhibit the highest catalytic activity in a 4 М KОН solution.</abstract><cop>New York</cop><pub>Springer US</pub><doi>10.1007/s11003-016-9874-8</doi><tpages>7</tpages></addata></record> |
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| ispartof | Materials science (New York, N.Y.), 2016, Vol.51 (4), p.548-554 |
| issn | 1068-820X 1573-885X |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1884108294 |
| source | SpringerLink Journals |
| subjects | Aluminum Aluminum alloys Aluminum base alloys Catalytic activity Characterization and Evaluation of Materials Chemistry and Materials Science Corrosion and anti-corrosives Corrosion resistance Electrodes Electrolytes Estimates Hydrogen Hydroxides Materials Science Medical societies Polarization Potassium hydroxides Solid Mechanics Structural Materials |
| title | Electrodes Based on Amorphous Metallic Aluminum Alloys in the Reactions of Hydrogen Release |
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