No Strain, No Gain? Enzymatic Ring‐Opening Polymerization of Strainless Aliphatic Macrolactones

Starting from readily available oleic and erucic acid, macrocyclic nonadecalactone (C19) and tricosalactone (C23) can be synthesized in polymerization grade purity in a four‐step reaction sequence. Ring‐opening polymerization (ROP) of these strainless macrolactones can be performed utilizing an enzy...

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Veröffentlicht in:	Macromolecular rapid communications. 2017-02, Vol.38 (4), p.np-n/a
Hauptverfasser:	Witt, Timo, Häußler, Manuel, Mecking, Stefan
Format:	Artikel
Sprache:	eng
Schlagworte:	Aliphatic compounds aliphatic polymacrolactones all‐aliphatic polyester material properties Candida antarctica lipase B Catalysts enzymatic ring‐opening polymerization Enzymes Fungal Proteins - chemistry Fungal Proteins - metabolism Lactones - chemistry Lactones - metabolism Lipase - chemistry Lipase - metabolism macrocyclic monolides Mechanical properties Molecular Structure Polyester resins Polyesters - chemistry Polyesters - metabolism Polyethylenes Polymerization Synthesis (chemistry)
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