Synthesis and Crystal Structures of the First Antimony(III) Aziridinides
The first antimony(III) aziridinyl derivatives are reported. Treatment of anhydrous SbCl3 with N-lithioaziridine Li(Azn) (Azn = NC2H4) afforded the structurally unique heterobimetallic lithium/antimony(III) amide complex [Li3Sb(μ3-Cl)2(μ-Azn)4(THF)2]∞ (1). Homoleptic Sb2(Azn)6 (2) has become ava...
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Veröffentlicht in: | Inorganic chemistry 2017-04, Vol.56 (8), p.4267-4270 |
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creator | Harmgarth, Nicole Liebing, Phil Zörner, Florian Silinskas, Mindaugas Burte, Edmund P Edelmann, Frank T |
description | The first antimony(III) aziridinyl derivatives are reported. Treatment of anhydrous SbCl3 with N-lithioaziridine Li(Azn) (Azn = NC2H4) afforded the structurally unique heterobimetallic lithium/antimony(III) amide complex [Li3Sb(μ3-Cl)2(μ-Azn)4(THF)2]∞ (1). Homoleptic Sb2(Azn)6 (2) has become available for the first time through an amide group exchange reaction between Sb(NMe2)3 and 3 equiv of aziridine. The low-melting Sb2(Azn)6 exhibits a “weak dimer” structure in the crystal. |
doi_str_mv | 10.1021/acs.inorgchem.7b00523 |
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title | Synthesis and Crystal Structures of the First Antimony(III) Aziridinides |
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