Schiff base thorium(iv) and uranium(iv) chloro complexes: synthesis, substitution and oxidation chemistry
New tetradentate Schiff base chloro complexes of U(iv) and Th(iv) are prepared by salt metathesis approaches. These compounds undergo clean salt metathesis with NaN to generate stable pseudo-trans azide compounds. The uranium dichloro complex also undergoes 2 e oxidation with excess NaNO to generate...
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| Veröffentlicht in: | Dalton transactions : an international journal of inorganic chemistry 2017-04, Vol.46 (15), p.4888-4892 |
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| container_end_page | 4892 |
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| container_issue | 15 |
| container_start_page | 4888 |
| container_title | Dalton transactions : an international journal of inorganic chemistry |
| container_volume | 46 |
| creator | Stobbe, Brian C Powell, Douglas R Thomson, Robert K |
| description | New tetradentate Schiff base chloro complexes of U(iv) and Th(iv) are prepared by salt metathesis approaches. These compounds undergo clean salt metathesis with NaN
to generate stable pseudo-trans azide compounds. The uranium dichloro complex also undergoes 2 e
oxidation with excess NaNO
to generate the uranyl derivative. All classes of complexes are characterized by single crystal X-ray diffraction and NMR spectroscopy. |
| doi_str_mv | 10.1039/c7dt00580f |
| format | Article |
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oxidation with excess NaNO
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oxidation with excess NaNO
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to generate stable pseudo-trans azide compounds. The uranium dichloro complex also undergoes 2 e
oxidation with excess NaNO
to generate the uranyl derivative. All classes of complexes are characterized by single crystal X-ray diffraction and NMR spectroscopy.</abstract><cop>England</cop><pmid>28349157</pmid><doi>10.1039/c7dt00580f</doi><tpages>5</tpages><orcidid>https://orcid.org/0000-0001-5316-5405</orcidid></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1477-9226 |
| ispartof | Dalton transactions : an international journal of inorganic chemistry, 2017-04, Vol.46 (15), p.4888-4892 |
| issn | 1477-9226 1477-9234 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1881771411 |
| source | Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection |
| title | Schiff base thorium(iv) and uranium(iv) chloro complexes: synthesis, substitution and oxidation chemistry |
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