Alkyl Formate Ester Synthesis by a Fungal Baeyer–Villiger Monooxygenase

We investigated Baeyer–Villiger monooxygenase (BVMO)‐mediated synthesis of alkyl formate esters, which are important flavor and fragrance products. A recombinant fungal BVMO from Aspergillus flavus was found to transform a selection of aliphatic aldehydes into alkyl formates with high regioselectivi...

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Veröffentlicht in:	Chembiochem : a European journal of chemical biology 2017-03, Vol.18 (6), p.515-517
Hauptverfasser:	Ferroni, Felix Martin, Tolmie, Carmien, Smit, Martha Sophia, Opperman, Diederik Johannes
Format:	Artikel
Sprache:	eng
Schlagworte:	Alcohols - metabolism aldehydes alkyl formate Aspergillus flavus Baeyer–Villiger monooxygenase biocatalysis Esters - chemical synthesis Esters - chemistry formate ester Formates - chemical synthesis Formates - chemistry Fungi - enzymology Mixed Function Oxygenases - chemistry Mixed Function Oxygenases - metabolism Stereoisomerism
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