Synthesis of Cyclic α‑Diazo-β-keto Sulfoxides in Batch and Continuous Flow

Diazo transfer to β-keto sulfoxides to form stable isolable α-diazo-β-keto sulfoxides has been achieved for the first time. Both monocyclic and benzofused ketone derived β-keto sulfoxides were successfully explored as substrates for diazo transfer. Use of continuous flow leads to isolation of the de...

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Veröffentlicht in:	Journal of organic chemistry 2017-04, Vol.82 (7), p.3666-3679
Hauptverfasser:	McCaw, Patrick G, Buckley, Naomi M, Eccles, Kevin S, Lawrence, Simon E, Maguire, Anita R, Collins, Stuart G
Format:	Artikel
Sprache:	eng
Online-Zugang:	Volltext
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