Visible-Light-Mediated Catalytic Hydroacylation of Dialkyl Azodicarboxylates by Graphite Flakes

Visible-Light-Mediated Catalytic Hydroacylation of Dialkyl Azodicarboxylates by Graphite Flakes

A novel and efficient metal-free catalyzed hydroacylation of dialkyl azodicarboxylates is reported. Graphite flakes were found to be the most efficient catalyst among other carbon-based materials to promote this reaction. This unprecedented catalytic activity can be expanded into a wide substrate sc...

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Veröffentlicht in:Organic letters 2017-04, Vol.19 (7), p.1760-1763
Hauptverfasser: Koutoulogenis, Giorgos S, Kokotou, Maroula G, Voutyritsa, Errika, Limnios, Dimitris, Kokotos, Christoforos G
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container_end_page 1763
container_issue 7
container_start_page 1760
container_title Organic letters
container_volume 19
creator Koutoulogenis, Giorgos S
Kokotou, Maroula G
Voutyritsa, Errika
Limnios, Dimitris
Kokotos, Christoforos G
description A novel and efficient metal-free catalyzed hydroacylation of dialkyl azodicarboxylates is reported. Graphite flakes were found to be the most efficient catalyst among other carbon-based materials to promote this reaction. This unprecedented catalytic activity can be expanded into a wide substrate scope of aliphatic aldehydes bearing various functional groups, leading to the corresponding products in good to excellent yields.
doi_str_mv 10.1021/acs.orglett.7b00519
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title Visible-Light-Mediated Catalytic Hydroacylation of Dialkyl Azodicarboxylates by Graphite Flakes
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