Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction

The phase relationships, magnetic transitions, and magnetocaloric effect (MCE) of MnCo1−xCuxGe (x=0–0.5) alloys have been investigated. The substitution of Cu for Co reduces the structural transition temperature between Ni2In-type hexagonal phase and TiNiSi-type orthorhombic phase. The Curie tempera...

Ausführliche Beschreibung

Gespeichert in:
Bibliographische Detailangaben
Veröffentlicht in:Materials & design 2017-01, Vol.114, p.531-536
Hauptverfasser: Zhang, Hu, Li, YaWei, Liu, EnKe, Tao, Kun, Wu, MeiLing, Wang, YiXu, Zhou, HouBo, Xue, YanJun, Cheng, Chen, Yan, Tim, Long, KeWen, Long, Yi
Format: Artikel
Sprache:eng
Schlagworte:
Online-Zugang:Volltext
Tags: Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
container_end_page 536
container_issue
container_start_page 531
container_title Materials & design
container_volume 114
creator Zhang, Hu
Li, YaWei
Liu, EnKe
Tao, Kun
Wu, MeiLing
Wang, YiXu
Zhou, HouBo
Xue, YanJun
Cheng, Chen
Yan, Tim
Long, KeWen
Long, Yi
description The phase relationships, magnetic transitions, and magnetocaloric effect (MCE) of MnCo1−xCuxGe (x=0–0.5) alloys have been investigated. The substitution of Cu for Co reduces the structural transition temperature between Ni2In-type hexagonal phase and TiNiSi-type orthorhombic phase. The Curie temperature of orthorhombic martensite (TCM) also decreases with increasing x from 0 to 0.2, which is likely due to the weakening of Co-Mn and/or Co-Co interactions by non-magnetic element Cu substitution for Co atoms. In addition, two successive first-order magnetic transitions, a ferromagnetic (FM) to antiferromagnetic (AFM)-like transition around T2 followed by an AFM to FM-like transition around T1, are observed for 0.17≤x≤0.27, which have not been reported in MnCoGe-based alloys so far. An inverse MCE is observed under low field changes and then a universal curve of ΔSM is successfully constructed, proving the applicability of universal curve for AFM materials with inverse MCE. Finally, the variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1. These new findings and related discussions are very helpful for future tailoring of magnetostructural coupling and metamagnetic transition in MM'X (M, M′=transition metals, X=carbon or boron group elements) alloys. [Display omitted] •For the first time, multiple first-order magnetic transitions are observed below TCMin MnCoGe-based alloys.•The variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1.•The universal curve of ΔSM peak is constructed, suggesting its applicability in AFM materials with inverse MCE.
doi_str_mv 10.1016/j.matdes.2016.10.066
format Article
fullrecord <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1880035949</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S026412751631365X</els_id><sourcerecordid>1880035949</sourcerecordid><originalsourceid>FETCH-LOGICAL-c405t-2ed4999955ff6a7635701f3bcb7ee24c99390b2d6f7a42c4cc93195870aa03c63</originalsourceid><addsrcrecordid>eNp9UL1OwzAQthBIlMIbMHhkSfFf4npBQhUUpFYsMFuucymuEqfYbtW-ATOPyJOQEGZuOd33J92H0DUlE0pocbuZNCaVECesuzpoQoriBI3oVPJMUCVP0YiwQmSUyfwcXcS4IYQxycUINctdndy2BtyYtYfkLE7B-OiSa33EzuOln7X0-_PrMNsd5oDL4Pbg8eqI7bvxa_jVmNQ2OMLWBNP7sPElhsMg6PgEwdieuERnlakjXP3tMXp7fHidPWWLl_nz7H6RWUHylDEoheomz6uqMLLguSS04iu7kgBMWKW4IitWFpU0gllhreJU5VNJjCHcFnyMbobcbWg_dhCTbly0UNfGQ7uLmk6nhPBcCdVJxSC1oY0xQKW3wTUmHDUlum9Xb_TQru7b7dGu3c52N9ige2PvIOhoHXgLpQtgky5b93_AD9zjh1g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1880035949</pqid></control><display><type>article</type><title>Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction</title><source>Alma/SFX Local Collection</source><creator>Zhang, Hu ; Li, YaWei ; Liu, EnKe ; Tao, Kun ; Wu, MeiLing ; Wang, YiXu ; Zhou, HouBo ; Xue, YanJun ; Cheng, Chen ; Yan, Tim ; Long, KeWen ; Long, Yi</creator><creatorcontrib>Zhang, Hu ; Li, YaWei ; Liu, EnKe ; Tao, Kun ; Wu, MeiLing ; Wang, YiXu ; Zhou, HouBo ; Xue, YanJun ; Cheng, Chen ; Yan, Tim ; Long, KeWen ; Long, Yi</creatorcontrib><description>The phase relationships, magnetic transitions, and magnetocaloric effect (MCE) of MnCo1−xCuxGe (x=0–0.5) alloys have been investigated. The substitution of Cu for Co reduces the structural transition temperature between Ni2In-type hexagonal phase and TiNiSi-type orthorhombic phase. The Curie temperature of orthorhombic martensite (TCM) also decreases with increasing x from 0 to 0.2, which is likely due to the weakening of Co-Mn and/or Co-Co interactions by non-magnetic element Cu substitution for Co atoms. In addition, two successive first-order magnetic transitions, a ferromagnetic (FM) to antiferromagnetic (AFM)-like transition around T2 followed by an AFM to FM-like transition around T1, are observed for 0.17≤x≤0.27, which have not been reported in MnCoGe-based alloys so far. An inverse MCE is observed under low field changes and then a universal curve of ΔSM is successfully constructed, proving the applicability of universal curve for AFM materials with inverse MCE. Finally, the variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1. These new findings and related discussions are very helpful for future tailoring of magnetostructural coupling and metamagnetic transition in MM'X (M, M′=transition metals, X=carbon or boron group elements) alloys. [Display omitted] •For the first time, multiple first-order magnetic transitions are observed below TCMin MnCoGe-based alloys.•The variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1.•The universal curve of ΔSM peak is constructed, suggesting its applicability in AFM materials with inverse MCE.</description><identifier>ISSN: 0264-1275</identifier><identifier>EISSN: 1873-4197</identifier><identifier>DOI: 10.1016/j.matdes.2016.10.066</identifier><language>eng</language><publisher>Elsevier Ltd</publisher><subject>Alloying additive ; Boron alloys ; Coupling ; Curie temperature ; Inverse ; Magnetic properties ; Magnetic transitions ; Magnetocaloric effect ; Martensitic transformations ; Orthorhombic phase ; Transition temperature</subject><ispartof>Materials &amp; design, 2017-01, Vol.114, p.531-536</ispartof><rights>2016 Elsevier Ltd</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c405t-2ed4999955ff6a7635701f3bcb7ee24c99390b2d6f7a42c4cc93195870aa03c63</citedby><cites>FETCH-LOGICAL-c405t-2ed4999955ff6a7635701f3bcb7ee24c99390b2d6f7a42c4cc93195870aa03c63</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Zhang, Hu</creatorcontrib><creatorcontrib>Li, YaWei</creatorcontrib><creatorcontrib>Liu, EnKe</creatorcontrib><creatorcontrib>Tao, Kun</creatorcontrib><creatorcontrib>Wu, MeiLing</creatorcontrib><creatorcontrib>Wang, YiXu</creatorcontrib><creatorcontrib>Zhou, HouBo</creatorcontrib><creatorcontrib>Xue, YanJun</creatorcontrib><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Yan, Tim</creatorcontrib><creatorcontrib>Long, KeWen</creatorcontrib><creatorcontrib>Long, Yi</creatorcontrib><title>Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction</title><title>Materials &amp; design</title><description>The phase relationships, magnetic transitions, and magnetocaloric effect (MCE) of MnCo1−xCuxGe (x=0–0.5) alloys have been investigated. The substitution of Cu for Co reduces the structural transition temperature between Ni2In-type hexagonal phase and TiNiSi-type orthorhombic phase. The Curie temperature of orthorhombic martensite (TCM) also decreases with increasing x from 0 to 0.2, which is likely due to the weakening of Co-Mn and/or Co-Co interactions by non-magnetic element Cu substitution for Co atoms. In addition, two successive first-order magnetic transitions, a ferromagnetic (FM) to antiferromagnetic (AFM)-like transition around T2 followed by an AFM to FM-like transition around T1, are observed for 0.17≤x≤0.27, which have not been reported in MnCoGe-based alloys so far. An inverse MCE is observed under low field changes and then a universal curve of ΔSM is successfully constructed, proving the applicability of universal curve for AFM materials with inverse MCE. Finally, the variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1. These new findings and related discussions are very helpful for future tailoring of magnetostructural coupling and metamagnetic transition in MM'X (M, M′=transition metals, X=carbon or boron group elements) alloys. [Display omitted] •For the first time, multiple first-order magnetic transitions are observed below TCMin MnCoGe-based alloys.•The variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1.•The universal curve of ΔSM peak is constructed, suggesting its applicability in AFM materials with inverse MCE.</description><subject>Alloying additive</subject><subject>Boron alloys</subject><subject>Coupling</subject><subject>Curie temperature</subject><subject>Inverse</subject><subject>Magnetic properties</subject><subject>Magnetic transitions</subject><subject>Magnetocaloric effect</subject><subject>Martensitic transformations</subject><subject>Orthorhombic phase</subject><subject>Transition temperature</subject><issn>0264-1275</issn><issn>1873-4197</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp9UL1OwzAQthBIlMIbMHhkSfFf4npBQhUUpFYsMFuucymuEqfYbtW-ATOPyJOQEGZuOd33J92H0DUlE0pocbuZNCaVECesuzpoQoriBI3oVPJMUCVP0YiwQmSUyfwcXcS4IYQxycUINctdndy2BtyYtYfkLE7B-OiSa33EzuOln7X0-_PrMNsd5oDL4Pbg8eqI7bvxa_jVmNQ2OMLWBNP7sPElhsMg6PgEwdieuERnlakjXP3tMXp7fHidPWWLl_nz7H6RWUHylDEoheomz6uqMLLguSS04iu7kgBMWKW4IitWFpU0gllhreJU5VNJjCHcFnyMbobcbWg_dhCTbly0UNfGQ7uLmk6nhPBcCdVJxSC1oY0xQKW3wTUmHDUlum9Xb_TQru7b7dGu3c52N9ige2PvIOhoHXgLpQtgky5b93_AD9zjh1g</recordid><startdate>20170115</startdate><enddate>20170115</enddate><creator>Zhang, Hu</creator><creator>Li, YaWei</creator><creator>Liu, EnKe</creator><creator>Tao, Kun</creator><creator>Wu, MeiLing</creator><creator>Wang, YiXu</creator><creator>Zhou, HouBo</creator><creator>Xue, YanJun</creator><creator>Cheng, Chen</creator><creator>Yan, Tim</creator><creator>Long, KeWen</creator><creator>Long, Yi</creator><general>Elsevier Ltd</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7QQ</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20170115</creationdate><title>Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction</title><author>Zhang, Hu ; Li, YaWei ; Liu, EnKe ; Tao, Kun ; Wu, MeiLing ; Wang, YiXu ; Zhou, HouBo ; Xue, YanJun ; Cheng, Chen ; Yan, Tim ; Long, KeWen ; Long, Yi</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c405t-2ed4999955ff6a7635701f3bcb7ee24c99390b2d6f7a42c4cc93195870aa03c63</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Alloying additive</topic><topic>Boron alloys</topic><topic>Coupling</topic><topic>Curie temperature</topic><topic>Inverse</topic><topic>Magnetic properties</topic><topic>Magnetic transitions</topic><topic>Magnetocaloric effect</topic><topic>Martensitic transformations</topic><topic>Orthorhombic phase</topic><topic>Transition temperature</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhang, Hu</creatorcontrib><creatorcontrib>Li, YaWei</creatorcontrib><creatorcontrib>Liu, EnKe</creatorcontrib><creatorcontrib>Tao, Kun</creatorcontrib><creatorcontrib>Wu, MeiLing</creatorcontrib><creatorcontrib>Wang, YiXu</creatorcontrib><creatorcontrib>Zhou, HouBo</creatorcontrib><creatorcontrib>Xue, YanJun</creatorcontrib><creatorcontrib>Cheng, Chen</creatorcontrib><creatorcontrib>Yan, Tim</creatorcontrib><creatorcontrib>Long, KeWen</creatorcontrib><creatorcontrib>Long, Yi</creatorcontrib><collection>CrossRef</collection><collection>Ceramic Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Materials &amp; design</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhang, Hu</au><au>Li, YaWei</au><au>Liu, EnKe</au><au>Tao, Kun</au><au>Wu, MeiLing</au><au>Wang, YiXu</au><au>Zhou, HouBo</au><au>Xue, YanJun</au><au>Cheng, Chen</au><au>Yan, Tim</au><au>Long, KeWen</au><au>Long, Yi</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction</atitle><jtitle>Materials &amp; design</jtitle><date>2017-01-15</date><risdate>2017</risdate><volume>114</volume><spage>531</spage><epage>536</epage><pages>531-536</pages><issn>0264-1275</issn><eissn>1873-4197</eissn><abstract>The phase relationships, magnetic transitions, and magnetocaloric effect (MCE) of MnCo1−xCuxGe (x=0–0.5) alloys have been investigated. The substitution of Cu for Co reduces the structural transition temperature between Ni2In-type hexagonal phase and TiNiSi-type orthorhombic phase. The Curie temperature of orthorhombic martensite (TCM) also decreases with increasing x from 0 to 0.2, which is likely due to the weakening of Co-Mn and/or Co-Co interactions by non-magnetic element Cu substitution for Co atoms. In addition, two successive first-order magnetic transitions, a ferromagnetic (FM) to antiferromagnetic (AFM)-like transition around T2 followed by an AFM to FM-like transition around T1, are observed for 0.17≤x≤0.27, which have not been reported in MnCoGe-based alloys so far. An inverse MCE is observed under low field changes and then a universal curve of ΔSM is successfully constructed, proving the applicability of universal curve for AFM materials with inverse MCE. Finally, the variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1. These new findings and related discussions are very helpful for future tailoring of magnetostructural coupling and metamagnetic transition in MM'X (M, M′=transition metals, X=carbon or boron group elements) alloys. [Display omitted] •For the first time, multiple first-order magnetic transitions are observed below TCMin MnCoGe-based alloys.•The variation of magnetic states is explained in terms of the expansion of nearest-neighbor Mn-Mn distance d1.•The universal curve of ΔSM peak is constructed, suggesting its applicability in AFM materials with inverse MCE.</abstract><pub>Elsevier Ltd</pub><doi>10.1016/j.matdes.2016.10.066</doi><tpages>6</tpages></addata></record>
fulltext fulltext
identifier ISSN: 0264-1275
ispartof Materials & design, 2017-01, Vol.114, p.531-536
issn 0264-1275
1873-4197
language eng
recordid cdi_proquest_miscellaneous_1880035949
source Alma/SFX Local Collection
subjects Alloying additive
Boron alloys
Coupling
Curie temperature
Inverse
Magnetic properties
Magnetic transitions
Magnetocaloric effect
Martensitic transformations
Orthorhombic phase
Transition temperature
title Multiple magnetic transitions in MnCo1−xCuxGe driven by changes in atom separation and exchange interaction
url https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2024-12-24T19%3A55%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Multiple%20magnetic%20transitions%20in%20MnCo1%E2%88%92xCuxGe%20driven%20by%20changes%20in%20atom%20separation%20and%20exchange%20interaction&rft.jtitle=Materials%20&%20design&rft.au=Zhang,%20Hu&rft.date=2017-01-15&rft.volume=114&rft.spage=531&rft.epage=536&rft.pages=531-536&rft.issn=0264-1275&rft.eissn=1873-4197&rft_id=info:doi/10.1016/j.matdes.2016.10.066&rft_dat=%3Cproquest_cross%3E1880035949%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1880035949&rft_id=info:pmid/&rft_els_id=S026412751631365X&rfr_iscdi=true