Bulk growth of undoped and Nd3+ doped zinc thiourea chloride (ZTC) monocrystal: Exploring the remarkably enhanced structural, optical, electrical and mechanical performance of Nd3+ doped ZTC crystal for NLO device applications
In current scenario good quality crystals are demanded for NLO device application hence present communication is aimed to grow bulk crystal and investigate the doping effect of rare earth element Nd3+ on structural, linear-nonlinear optical, luminescence, mechanical and dielectric properties of zinc...
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| description | In current scenario good quality crystals are demanded for NLO device application hence present communication is aimed to grow bulk crystal and investigate the doping effect of rare earth element Nd3+ on structural, linear-nonlinear optical, luminescence, mechanical and dielectric properties of zinc thiourea chloride (ZTC) crystal. The ZTC crystal of dimension 21×10×8mm3 and the Nd3+ doped ZTC crystal of dimension 27×17×5mm3 have been grown from aqueous solution by slow evaporation technique. The elemental analysis of Nd3+ doped ZTC single crystal has been performed by means of energy dispersive spectroscopic technique. The powder X-ray diffraction technique has been employed to confirm the crystalline phase and identify the effect of Nd3+ doping on structural dimensions of ZTC crystal. The grown crystals have been characterized by UV–Vis–NIR study in the range of 190–1100nm to ascertain the enhancement in optical transparency of ZTC crystal facilitated by dopant Nd3+. The recorded transmittance data has been utilized to investigate the vital optical constants of grown crystals. The second order nonlinear optical behavior of grown crystals has been evaluated by means of Kurtz-Perry test and the second harmonic generation efficiency of Nd3+ doped ZTC crystal is found to be 1.24 times higher than ZTC crystal. The luminescence analysis has been performed to examine the electronic purity and the color centered photoluminescence emission nature of pure and Nd3+ doped ZTC crystals. The influence of Nd3+ ion on mechanical behavior of ZTC crystal has been investigated by means of microhardness studies. The nature of dielectric constant and dielectric loss of pure and Nd3+ doped ZTC crystal has been examined in the range of 40–100°C under dielectric study. The Z-scan technique has been employed using the He-Ne laser to investigate the third order nonlinear optical (TONLO) nature of Nd3+ doped ZTC single crystal. The magnitude of TONLO susceptibility, absorption coefficient and refraction has been determined using the Z-scan transmittance data.
[Display omitted]
•Growth of ZTC (21×10×8mm3) and Nd3+ doped ZTC (27×17×5mm3) bulk crystal is achieved.•Nd3+ doped ZTC crystal is excellent TONLO crystal with χ3 of magnitude 5.82×10−3esu.•Doping of Nd3+ significantly improved the optical parameters of ZTC crystal.•Enhanced SHG efficiency of Nd3+ doped ZTC crystal is 1.24 times that of ZTC crystal.•Lower dielectrics of Nd3+ doped ZTC crystal are vital for optoelectronics appl |
| doi_str_mv | 10.1016/j.optlastec.2016.11.020 |
| format | Article |
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[Display omitted]
•Growth of ZTC (21×10×8mm3) and Nd3+ doped ZTC (27×17×5mm3) bulk crystal is achieved.•Nd3+ doped ZTC crystal is excellent TONLO crystal with χ3 of magnitude 5.82×10−3esu.•Doping of Nd3+ significantly improved the optical parameters of ZTC crystal.•Enhanced SHG efficiency of Nd3+ doped ZTC crystal is 1.24 times that of ZTC crystal.•Lower dielectrics of Nd3+ doped ZTC crystal are vital for optoelectronics applications.</description><identifier>ISSN: 0030-3992</identifier><identifier>EISSN: 1879-2545</identifier><identifier>DOI: 10.1016/j.optlastec.2016.11.020</identifier><language>eng</language><publisher>Kidlington: Elsevier Ltd</publisher><subject>Absorptivity ; Chlorides ; Crystal growth ; Crystal structure ; Crystals ; Devices ; Dielectric loss ; Dielectric properties ; Dielectric studies ; Doping ; Influence ; Luminescence ; Mechanical properties ; Mechanical studies ; Microhardness ; Neodymium ; Nonlinear optical materials ; Nonlinearity ; Optical properties ; Optical studies ; Permittivity ; Photoluminescence ; Rare earth elements ; Second harmonic generation ; Single crystals ; Thioureas ; Trace elements ; Transmittance ; X ray powder diffraction ; X-ray diffraction ; Zinc</subject><ispartof>Optics and laser technology, 2017-05, Vol.90, p.190-196</ispartof><rights>2016 Elsevier Ltd</rights><rights>Copyright Elsevier BV May 1, 2017</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c306t-a638283c66bf3756765628a5d8d2b1aff8fb5b338863e3ea1eee36d64e60183</citedby><cites>FETCH-LOGICAL-c306t-a638283c66bf3756765628a5d8d2b1aff8fb5b338863e3ea1eee36d64e60183</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://www.sciencedirect.com/science/article/pii/S0030399216311422$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,776,780,3536,27903,27904,65309</link.rule.ids></links><search><creatorcontrib>Anis, Mohd</creatorcontrib><creatorcontrib>Muley, Gajanan.G.</creatorcontrib><title>Bulk growth of undoped and Nd3+ doped zinc thiourea chloride (ZTC) monocrystal: Exploring the remarkably enhanced structural, optical, electrical and mechanical performance of Nd3+ doped ZTC crystal for NLO device applications</title><title>Optics and laser technology</title><description>In current scenario good quality crystals are demanded for NLO device application hence present communication is aimed to grow bulk crystal and investigate the doping effect of rare earth element Nd3+ on structural, linear-nonlinear optical, luminescence, mechanical and dielectric properties of zinc thiourea chloride (ZTC) crystal. The ZTC crystal of dimension 21×10×8mm3 and the Nd3+ doped ZTC crystal of dimension 27×17×5mm3 have been grown from aqueous solution by slow evaporation technique. The elemental analysis of Nd3+ doped ZTC single crystal has been performed by means of energy dispersive spectroscopic technique. The powder X-ray diffraction technique has been employed to confirm the crystalline phase and identify the effect of Nd3+ doping on structural dimensions of ZTC crystal. The grown crystals have been characterized by UV–Vis–NIR study in the range of 190–1100nm to ascertain the enhancement in optical transparency of ZTC crystal facilitated by dopant Nd3+. The recorded transmittance data has been utilized to investigate the vital optical constants of grown crystals. The second order nonlinear optical behavior of grown crystals has been evaluated by means of Kurtz-Perry test and the second harmonic generation efficiency of Nd3+ doped ZTC crystal is found to be 1.24 times higher than ZTC crystal. The luminescence analysis has been performed to examine the electronic purity and the color centered photoluminescence emission nature of pure and Nd3+ doped ZTC crystals. The influence of Nd3+ ion on mechanical behavior of ZTC crystal has been investigated by means of microhardness studies. The nature of dielectric constant and dielectric loss of pure and Nd3+ doped ZTC crystal has been examined in the range of 40–100°C under dielectric study. The Z-scan technique has been employed using the He-Ne laser to investigate the third order nonlinear optical (TONLO) nature of Nd3+ doped ZTC single crystal. The magnitude of TONLO susceptibility, absorption coefficient and refraction has been determined using the Z-scan transmittance data.
[Display omitted]
•Growth of ZTC (21×10×8mm3) and Nd3+ doped ZTC (27×17×5mm3) bulk crystal is achieved.•Nd3+ doped ZTC crystal is excellent TONLO crystal with χ3 of magnitude 5.82×10−3esu.•Doping of Nd3+ significantly improved the optical parameters of ZTC crystal.•Enhanced SHG efficiency of Nd3+ doped ZTC crystal is 1.24 times that of ZTC crystal.•Lower dielectrics of Nd3+ doped ZTC crystal are vital for optoelectronics applications.</description><subject>Absorptivity</subject><subject>Chlorides</subject><subject>Crystal growth</subject><subject>Crystal structure</subject><subject>Crystals</subject><subject>Devices</subject><subject>Dielectric loss</subject><subject>Dielectric properties</subject><subject>Dielectric studies</subject><subject>Doping</subject><subject>Influence</subject><subject>Luminescence</subject><subject>Mechanical properties</subject><subject>Mechanical studies</subject><subject>Microhardness</subject><subject>Neodymium</subject><subject>Nonlinear optical materials</subject><subject>Nonlinearity</subject><subject>Optical properties</subject><subject>Optical studies</subject><subject>Permittivity</subject><subject>Photoluminescence</subject><subject>Rare earth elements</subject><subject>Second harmonic generation</subject><subject>Single crystals</subject><subject>Thioureas</subject><subject>Trace elements</subject><subject>Transmittance</subject><subject>X ray powder diffraction</subject><subject>X-ray diffraction</subject><subject>Zinc</subject><issn>0030-3992</issn><issn>1879-2545</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqFUU1v1DAQjRBILIXfgCUuRZBgx4nX4dauyoe0ag_0xMVynEnXWycOtlNYfi6_hEm3QogLJ8_Y7808v5dlLxktGGXi3b7wU3I6JjBFiRcFYwUt6aNsxeS6ycu6qh9nK0o5zXnTlE-zZzHuKaWVqPkq-3U-u1tyE_z3tCO-J_PY-Qk6oseOXHb8DTm2P-1oSNpZPwfQxOycD7YDcvr1evOaDH70Jhxi0u49ufgxLY_jDcKBBBh0uNWtOxAYd3o0OCumMJs0B-3eEpRuzVKAA5PCUt-vHsAg-r6dIPQ-DAt3EfiXKFxOHvYShJDL7RXp4M4iUE-TQ3ayfozPsye9dhFePJwn2ZcPF9ebT_n26uPnzdk2N5yKlGvBZSm5EaLt-boWa1GLUuq6k13ZMt33sm_rlnMpBQcOmgEAF52oQFAm-Ul2epw6Bf9thpjUYKMB5_QIfo6KSYkZoOk1Ql_9A92jryNqU6ypGsEqjAdR6yPKBB9jgF5NwaKbB8WoWpJXe_UnebUkrxhTmDwyz45MwN_eWQgqGguL9zagy6rz9r8zfgNe-78U</recordid><startdate>20170501</startdate><enddate>20170501</enddate><creator>Anis, Mohd</creator><creator>Muley, Gajanan.G.</creator><general>Elsevier Ltd</general><general>Elsevier BV</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7SP</scope><scope>7U5</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>H8D</scope><scope>L7M</scope></search><sort><creationdate>20170501</creationdate><title>Bulk growth of undoped and Nd3+ doped zinc thiourea chloride (ZTC) monocrystal: Exploring the remarkably enhanced structural, optical, electrical and mechanical performance of Nd3+ doped ZTC crystal for NLO device applications</title><author>Anis, Mohd ; Muley, Gajanan.G.</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c306t-a638283c66bf3756765628a5d8d2b1aff8fb5b338863e3ea1eee36d64e60183</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Absorptivity</topic><topic>Chlorides</topic><topic>Crystal growth</topic><topic>Crystal structure</topic><topic>Crystals</topic><topic>Devices</topic><topic>Dielectric loss</topic><topic>Dielectric properties</topic><topic>Dielectric studies</topic><topic>Doping</topic><topic>Influence</topic><topic>Luminescence</topic><topic>Mechanical properties</topic><topic>Mechanical studies</topic><topic>Microhardness</topic><topic>Neodymium</topic><topic>Nonlinear optical materials</topic><topic>Nonlinearity</topic><topic>Optical properties</topic><topic>Optical studies</topic><topic>Permittivity</topic><topic>Photoluminescence</topic><topic>Rare earth elements</topic><topic>Second harmonic generation</topic><topic>Single crystals</topic><topic>Thioureas</topic><topic>Trace elements</topic><topic>Transmittance</topic><topic>X ray powder diffraction</topic><topic>X-ray diffraction</topic><topic>Zinc</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Anis, Mohd</creatorcontrib><creatorcontrib>Muley, Gajanan.G.</creatorcontrib><collection>CrossRef</collection><collection>Electronics & Communications Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Aerospace Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Optics and laser technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Anis, Mohd</au><au>Muley, Gajanan.G.</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Bulk growth of undoped and Nd3+ doped zinc thiourea chloride (ZTC) monocrystal: Exploring the remarkably enhanced structural, optical, electrical and mechanical performance of Nd3+ doped ZTC crystal for NLO device applications</atitle><jtitle>Optics and laser technology</jtitle><date>2017-05-01</date><risdate>2017</risdate><volume>90</volume><spage>190</spage><epage>196</epage><pages>190-196</pages><issn>0030-3992</issn><eissn>1879-2545</eissn><abstract>In current scenario good quality crystals are demanded for NLO device application hence present communication is aimed to grow bulk crystal and investigate the doping effect of rare earth element Nd3+ on structural, linear-nonlinear optical, luminescence, mechanical and dielectric properties of zinc thiourea chloride (ZTC) crystal. The ZTC crystal of dimension 21×10×8mm3 and the Nd3+ doped ZTC crystal of dimension 27×17×5mm3 have been grown from aqueous solution by slow evaporation technique. The elemental analysis of Nd3+ doped ZTC single crystal has been performed by means of energy dispersive spectroscopic technique. The powder X-ray diffraction technique has been employed to confirm the crystalline phase and identify the effect of Nd3+ doping on structural dimensions of ZTC crystal. The grown crystals have been characterized by UV–Vis–NIR study in the range of 190–1100nm to ascertain the enhancement in optical transparency of ZTC crystal facilitated by dopant Nd3+. The recorded transmittance data has been utilized to investigate the vital optical constants of grown crystals. The second order nonlinear optical behavior of grown crystals has been evaluated by means of Kurtz-Perry test and the second harmonic generation efficiency of Nd3+ doped ZTC crystal is found to be 1.24 times higher than ZTC crystal. The luminescence analysis has been performed to examine the electronic purity and the color centered photoluminescence emission nature of pure and Nd3+ doped ZTC crystals. The influence of Nd3+ ion on mechanical behavior of ZTC crystal has been investigated by means of microhardness studies. The nature of dielectric constant and dielectric loss of pure and Nd3+ doped ZTC crystal has been examined in the range of 40–100°C under dielectric study. The Z-scan technique has been employed using the He-Ne laser to investigate the third order nonlinear optical (TONLO) nature of Nd3+ doped ZTC single crystal. The magnitude of TONLO susceptibility, absorption coefficient and refraction has been determined using the Z-scan transmittance data.
[Display omitted]
•Growth of ZTC (21×10×8mm3) and Nd3+ doped ZTC (27×17×5mm3) bulk crystal is achieved.•Nd3+ doped ZTC crystal is excellent TONLO crystal with χ3 of magnitude 5.82×10−3esu.•Doping of Nd3+ significantly improved the optical parameters of ZTC crystal.•Enhanced SHG efficiency of Nd3+ doped ZTC crystal is 1.24 times that of ZTC crystal.•Lower dielectrics of Nd3+ doped ZTC crystal are vital for optoelectronics applications.</abstract><cop>Kidlington</cop><pub>Elsevier Ltd</pub><doi>10.1016/j.optlastec.2016.11.020</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 0030-3992 |
| ispartof | Optics and laser technology, 2017-05, Vol.90, p.190-196 |
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| source | Elsevier ScienceDirect Journals |
| subjects | Absorptivity Chlorides Crystal growth Crystal structure Crystals Devices Dielectric loss Dielectric properties Dielectric studies Doping Influence Luminescence Mechanical properties Mechanical studies Microhardness Neodymium Nonlinear optical materials Nonlinearity Optical properties Optical studies Permittivity Photoluminescence Rare earth elements Second harmonic generation Single crystals Thioureas Trace elements Transmittance X ray powder diffraction X-ray diffraction Zinc |
| title | Bulk growth of undoped and Nd3+ doped zinc thiourea chloride (ZTC) monocrystal: Exploring the remarkably enhanced structural, optical, electrical and mechanical performance of Nd3+ doped ZTC crystal for NLO device applications |
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