Copper‐Catalyzed Remote para‐C−H Functionalization of Anilines with Sodium and Lithium Sulfinates

A copper‐catalyzed, cross‐dehydrogenative coupling of anilines with sodium and lithium sulfinates was developed. By using a cooperative reaction system with Mn(OAc)3 as stoichiometric co‐oxidant a highly selective para‐functionalization of anilines was accomplished. Various functional groups were to...

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Veröffentlicht in:	Chemistry : a European journal 2017-01, Vol.23 (1), p.96-100
Hauptverfasser:	Liang, Shuai, Bolte, Michael, Manolikakes, Georg
Format:	Artikel
Sprache:	eng
Schlagworte:	Aniline Catalysts copper Coupling C−H functionalization Functional groups Lithium manganese site-selectivity Sodium sulfone Synthesis
Online-Zugang:	Volltext
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