Advancements in rationally designed PGM-free fuel cell catalysts derived from metal-organic frameworks
Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, w...
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Veröffentlicht in: | Materials horizons 2017-01, Vol.4 (1), p.2-37 |
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description | Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, we summarize the recent advancements in design, synthesis and characterization of MOF-derived ORR catalysts and their performances in acidic and alkaline media. We also discuss the key challenges such as durability and activity enhancement critical in moving forward this emerging electrocatalyst science.
A comprehensive review revealed metal-organic frameworks as promising precursors for preparing highly active PGM-free electro-catalysts for oxygen reduction reaction. |
doi_str_mv | 10.1039/c6mh00344c |
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A comprehensive review revealed metal-organic frameworks as promising precursors for preparing highly active PGM-free electro-catalysts for oxygen reduction reaction.</description><subject>Catalysis</subject><subject>Catalysts</subject><subject>Chemical reactions</subject><subject>Efficiency</subject><subject>Electrocatalysts</subject><subject>Metal-organic frameworks</subject><subject>Platinum</subject><subject>Reduction (metal working)</subject><issn>2051-6347</issn><issn>2051-6355</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNp90E1LAzEQBuAgChbtxbuw3kRYnWw-mj2Woq3Qogc9L9lkUlf3oybbSv-9qZV685KE4Zlh8hJyQeGWAsvvjGzeABjn5ogMMhA0lUyI48Obj07JMIR3AKCMC1AwIG5sN7o12GDbh6RqE6_7qmt1XW8Ti6FatmiT5-kidR4xcWusE4N1PHSv622IPRZ9tYnI-a5JGozltPNL3VYmlnSDX53_COfkxOk64PD3PiOvD_cvk1k6f5o-Tsbz1HBB-1ToDJTgCo0FITI5sqhKxxy3OUJmJFLOc1UyKblRCmVugVmKsixlLrUcsTNyvZ-78t3nGkNfNFXYLaxb7NahoErFz4PK8khv9tT4LgSPrlj5qtF-W1AodnkWE7mY_eQ5ifhqj30wB_eXd7GyLprL_wz7BgGzfe8</recordid><startdate>20170101</startdate><enddate>20170101</enddate><creator>Barkholtz, Heather M</creator><creator>Liu, Di-Jia</creator><scope>AAYXX</scope><scope>CITATION</scope><scope>7SR</scope><scope>7TB</scope><scope>7U5</scope><scope>8BQ</scope><scope>8FD</scope><scope>F28</scope><scope>FR3</scope><scope>JG9</scope><scope>L7M</scope><orcidid>https://orcid.org/0000-0003-1747-028X</orcidid></search><sort><creationdate>20170101</creationdate><title>Advancements in rationally designed PGM-free fuel cell catalysts derived from metal-organic frameworks</title><author>Barkholtz, Heather M ; Liu, Di-Jia</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c451t-5a208548ecd055267de8bf3f4d9e02c6e14498b3664c88e69d03d1e6bb696a673</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Catalysis</topic><topic>Catalysts</topic><topic>Chemical reactions</topic><topic>Efficiency</topic><topic>Electrocatalysts</topic><topic>Metal-organic frameworks</topic><topic>Platinum</topic><topic>Reduction (metal working)</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Barkholtz, Heather M</creatorcontrib><creatorcontrib>Liu, Di-Jia</creatorcontrib><collection>CrossRef</collection><collection>Engineered Materials Abstracts</collection><collection>Mechanical & Transportation Engineering Abstracts</collection><collection>Solid State and Superconductivity Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>ANTE: Abstracts in New Technology & Engineering</collection><collection>Engineering Research Database</collection><collection>Materials Research Database</collection><collection>Advanced Technologies Database with Aerospace</collection><jtitle>Materials horizons</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Barkholtz, Heather M</au><au>Liu, Di-Jia</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Advancements in rationally designed PGM-free fuel cell catalysts derived from metal-organic frameworks</atitle><jtitle>Materials horizons</jtitle><date>2017-01-01</date><risdate>2017</risdate><volume>4</volume><issue>1</issue><spage>2</spage><epage>37</epage><pages>2-37</pages><issn>2051-6347</issn><eissn>2051-6355</eissn><abstract>Over the past several years, metal-organic framework (MOF)-derived platinum group metal free (PGM-free) electrocatalysts have gained considerable attention due to their high efficiency and low cost as potential replacement for platinum in catalyzing oxygen reduction reaction (ORR). In this review, we summarize the recent advancements in design, synthesis and characterization of MOF-derived ORR catalysts and their performances in acidic and alkaline media. We also discuss the key challenges such as durability and activity enhancement critical in moving forward this emerging electrocatalyst science.
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subjects | Catalysis Catalysts Chemical reactions Efficiency Electrocatalysts Metal-organic frameworks Platinum Reduction (metal working) |
title | Advancements in rationally designed PGM-free fuel cell catalysts derived from metal-organic frameworks |
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