Self-oscillating microgels with Fe(phen) sub(3) catalyst induced by the BZ reaction under acid-free conditions
A novel self-oscillating microgels were prepared by copolymerization N-isopropylacrylamide (NIPAAm), organic acid and iron(II) 5-acrylamide-1,10-phenanthroline-bi (1,10-phenanthroline) (Fe(phen) sub(3)), the catalyst for the Belousov-Zhabotinsky (BZ) reaction. The microgels were characterized by FTI...
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| Veröffentlicht in: | Journal of polymer research 2017-01, Vol.24 (2), p.1-6 |
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| creator | Ren, Jie Gu, Jinfen Tao, Li He, Jihong Yang, Wu |
| description | A novel self-oscillating microgels were prepared by copolymerization N-isopropylacrylamide (NIPAAm), organic acid and iron(II) 5-acrylamide-1,10-phenanthroline-bi (1,10-phenanthroline) (Fe(phen) sub(3)), the catalyst for the Belousov-Zhabotinsky (BZ) reaction. The microgels were characterized by FTIR spectroscopy and scanning electron microscope (SEM). In order to illustrate the self-oscillating mechanism, the static water contact angles of the oxidized and reduced states of self-oscillating microgels were measured. In addition, the self-oscillating behaviors of the microgels were investigated in BZ system under acid-free conditions. Both the redox potential and transmittance self-oscillating were observed at room temperature. |
| doi_str_mv | 10.1007/s10965-016-1139-6 |
| format | Article |
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The microgels were characterized by FTIR spectroscopy and scanning electron microscope (SEM). In order to illustrate the self-oscillating mechanism, the static water contact angles of the oxidized and reduced states of self-oscillating microgels were measured. In addition, the self-oscillating behaviors of the microgels were investigated in BZ system under acid-free conditions. 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The microgels were characterized by FTIR spectroscopy and scanning electron microscope (SEM). In order to illustrate the self-oscillating mechanism, the static water contact angles of the oxidized and reduced states of self-oscillating microgels were measured. In addition, the self-oscillating behaviors of the microgels were investigated in BZ system under acid-free conditions. 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The microgels were characterized by FTIR spectroscopy and scanning electron microscope (SEM). In order to illustrate the self-oscillating mechanism, the static water contact angles of the oxidized and reduced states of self-oscillating microgels were measured. In addition, the self-oscillating behaviors of the microgels were investigated in BZ system under acid-free conditions. Both the redox potential and transmittance self-oscillating were observed at room temperature.</abstract><doi>10.1007/s10965-016-1139-6</doi></addata></record> |
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| source | Springer Nature - Complete Springer Journals |
| subjects | Catalysts Contact Copolymerization Fourier transforms Infrared spectroscopy Microgels Scanning electron microscopy Transmittance |
| title | Self-oscillating microgels with Fe(phen) sub(3) catalyst induced by the BZ reaction under acid-free conditions |
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