Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes
•Nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel was prepared by a two-step polymerization method.•Nano-TiO2 was used to give the photocatalytic activity of the composite hydrogel.•The composite hydrogel exhibited high efficiency of acid fuchsin dye removal rate under UV irradiatio...
Gespeichert in:
| Veröffentlicht in: | Separation and purification technology 2017-04, Vol.176, p.193-199 |
|---|---|
| Hauptverfasser: | , , , , |
| Format: | Artikel |
| Sprache: | eng |
| Schlagworte: | |
| Online-Zugang: | Volltext |
| Tags: |
Tag hinzufügen
Keine Tags, Fügen Sie den ersten Tag hinzu!
|
| container_end_page | 199 |
|---|---|
| container_issue | |
| container_start_page | 193 |
| container_title | Separation and purification technology |
| container_volume | 176 |
| creator | Zhou, Jianhua Hao, Bianzhi Wang, Linben Ma, Jianzhong Cheng, Wenjing |
| description | •Nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel was prepared by a two-step polymerization method.•Nano-TiO2 was used to give the photocatalytic activity of the composite hydrogel.•The composite hydrogel exhibited high efficiency of acid fuchsin dye removal rate under UV irradiation.
Nano-TiO2/chitosan/poly(N-isopropylacrylamide) (nano-TiO2/CS/PNIPAAm) composite hydrogel was prepared by a two-step polymerization method, and nano-TiO2 can endow the composite hydrogel with photocatalytic activity. The nano-TiO2/CS/PNIPAAm composite hydrogel was characterized by FT-IR and SEM. The properties of dye adsorption and photocatalytic degradation were investigated. The results indicated that dye adsorption was strongly influenced by solution pH and the acid fuchsin (AF) removal rate was maximum at pH=4. The dye removal rate decreased slightly with increasing temperature, and the composite hydrogel adsorbing AF dyes floated on the solution surface at 40°C and could be readily removed from the aqueous solution. Kinetics analysis indicated that the dye adsorption by nano-TiO2/CS/PNIPAAm composite hydrogel conformed to pseudo-second order model. Moreover, nano-TiO2/CS/PNIPAAm composite hydrogel exhibited high efficiency of photocatalytic degradation for AF dyes, and AF dye removal rate reached 90.5% under UV irradiation for 160min. |
| doi_str_mv | 10.1016/j.seppur.2016.11.069 |
| format | Article |
| fullrecord | <record><control><sourceid>proquest_cross</sourceid><recordid>TN_cdi_proquest_miscellaneous_1879989443</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><els_id>S1383586616308437</els_id><sourcerecordid>1879989443</sourcerecordid><originalsourceid>FETCH-LOGICAL-c475t-4be2a05ad66e8c70ce07dfca1c8428fe87e35d4ff5a94cfd79a4722c7a86f53b3</originalsourceid><addsrcrecordid>eNqNUctO3DAUjVCRoMAfsMiSLpKxEye2N5Uq1EIlVFjA2jLX14xHSezaGaT0N_jhepquEZv70rnnPk5RXFJSU0L7za5OGMI-1k3Oakpr0suj4pQK3lYtl-xTjlvRVp3o-5Pic0o7Qiinojkt3h4iBh317PxU6smUsM0ZzBjdn7XobTnpyVeP7r7ZwNbNPulpE_ywXP2qXPIh-rAMGmI2ozP4pQQ_Bp_cjOV2MdG_4PCP2c2p1CEMDlZi62MZcfSvejgMySUHpVkwnRfHVg8JL_77s-Lpx_fH69vq7v7m5_W3uwoY7-aKPWOjSadN36MATgAJNxY0BcEaYVFwbDvDrO20ZGANl5rxpgGuRW-79rk9K65W3nzC7z2mWY0uAQ6DntDvk8r_k1JIxtoPQDvJZF6LZihboRB9ShGtCtGNOi6KEnWQS-3UKpc6yKUoVVmu3PZ1bcN88avDqBI4nACNiwizMt69T_AXnZqk4A</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1859494751</pqid></control><display><type>article</type><title>Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes</title><source>ScienceDirect Journals (5 years ago - present)</source><creator>Zhou, Jianhua ; Hao, Bianzhi ; Wang, Linben ; Ma, Jianzhong ; Cheng, Wenjing</creator><creatorcontrib>Zhou, Jianhua ; Hao, Bianzhi ; Wang, Linben ; Ma, Jianzhong ; Cheng, Wenjing</creatorcontrib><description>•Nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel was prepared by a two-step polymerization method.•Nano-TiO2 was used to give the photocatalytic activity of the composite hydrogel.•The composite hydrogel exhibited high efficiency of acid fuchsin dye removal rate under UV irradiation.
Nano-TiO2/chitosan/poly(N-isopropylacrylamide) (nano-TiO2/CS/PNIPAAm) composite hydrogel was prepared by a two-step polymerization method, and nano-TiO2 can endow the composite hydrogel with photocatalytic activity. The nano-TiO2/CS/PNIPAAm composite hydrogel was characterized by FT-IR and SEM. The properties of dye adsorption and photocatalytic degradation were investigated. The results indicated that dye adsorption was strongly influenced by solution pH and the acid fuchsin (AF) removal rate was maximum at pH=4. The dye removal rate decreased slightly with increasing temperature, and the composite hydrogel adsorbing AF dyes floated on the solution surface at 40°C and could be readily removed from the aqueous solution. Kinetics analysis indicated that the dye adsorption by nano-TiO2/CS/PNIPAAm composite hydrogel conformed to pseudo-second order model. Moreover, nano-TiO2/CS/PNIPAAm composite hydrogel exhibited high efficiency of photocatalytic degradation for AF dyes, and AF dye removal rate reached 90.5% under UV irradiation for 160min.</description><identifier>ISSN: 1383-5866</identifier><identifier>EISSN: 1873-3794</identifier><identifier>DOI: 10.1016/j.seppur.2016.11.069</identifier><language>eng</language><publisher>Elsevier B.V</publisher><subject>Acid fuchsin ; Adsorption ; Chitosan ; Composite hydrogel ; Degradation ; Dyes ; Hydrogels ; Nano-TiO2 ; Nanostructure ; Photocatalysis ; Photocatalytic activity ; Poly(N-isopropylacrylamide) ; Surface chemistry</subject><ispartof>Separation and purification technology, 2017-04, Vol.176, p.193-199</ispartof><rights>2016 Elsevier B.V.</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c475t-4be2a05ad66e8c70ce07dfca1c8428fe87e35d4ff5a94cfd79a4722c7a86f53b3</citedby><cites>FETCH-LOGICAL-c475t-4be2a05ad66e8c70ce07dfca1c8428fe87e35d4ff5a94cfd79a4722c7a86f53b3</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><linktohtml>$$Uhttps://dx.doi.org/10.1016/j.seppur.2016.11.069$$EHTML$$P50$$Gelsevier$$H</linktohtml><link.rule.ids>314,780,784,3550,27924,27925,45995</link.rule.ids></links><search><creatorcontrib>Zhou, Jianhua</creatorcontrib><creatorcontrib>Hao, Bianzhi</creatorcontrib><creatorcontrib>Wang, Linben</creatorcontrib><creatorcontrib>Ma, Jianzhong</creatorcontrib><creatorcontrib>Cheng, Wenjing</creatorcontrib><title>Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes</title><title>Separation and purification technology</title><description>•Nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel was prepared by a two-step polymerization method.•Nano-TiO2 was used to give the photocatalytic activity of the composite hydrogel.•The composite hydrogel exhibited high efficiency of acid fuchsin dye removal rate under UV irradiation.
Nano-TiO2/chitosan/poly(N-isopropylacrylamide) (nano-TiO2/CS/PNIPAAm) composite hydrogel was prepared by a two-step polymerization method, and nano-TiO2 can endow the composite hydrogel with photocatalytic activity. The nano-TiO2/CS/PNIPAAm composite hydrogel was characterized by FT-IR and SEM. The properties of dye adsorption and photocatalytic degradation were investigated. The results indicated that dye adsorption was strongly influenced by solution pH and the acid fuchsin (AF) removal rate was maximum at pH=4. The dye removal rate decreased slightly with increasing temperature, and the composite hydrogel adsorbing AF dyes floated on the solution surface at 40°C and could be readily removed from the aqueous solution. Kinetics analysis indicated that the dye adsorption by nano-TiO2/CS/PNIPAAm composite hydrogel conformed to pseudo-second order model. Moreover, nano-TiO2/CS/PNIPAAm composite hydrogel exhibited high efficiency of photocatalytic degradation for AF dyes, and AF dye removal rate reached 90.5% under UV irradiation for 160min.</description><subject>Acid fuchsin</subject><subject>Adsorption</subject><subject>Chitosan</subject><subject>Composite hydrogel</subject><subject>Degradation</subject><subject>Dyes</subject><subject>Hydrogels</subject><subject>Nano-TiO2</subject><subject>Nanostructure</subject><subject>Photocatalysis</subject><subject>Photocatalytic activity</subject><subject>Poly(N-isopropylacrylamide)</subject><subject>Surface chemistry</subject><issn>1383-5866</issn><issn>1873-3794</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2017</creationdate><recordtype>article</recordtype><recordid>eNqNUctO3DAUjVCRoMAfsMiSLpKxEye2N5Uq1EIlVFjA2jLX14xHSezaGaT0N_jhepquEZv70rnnPk5RXFJSU0L7za5OGMI-1k3Oakpr0suj4pQK3lYtl-xTjlvRVp3o-5Pic0o7Qiinojkt3h4iBh317PxU6smUsM0ZzBjdn7XobTnpyVeP7r7ZwNbNPulpE_ywXP2qXPIh-rAMGmI2ozP4pQQ_Bp_cjOV2MdG_4PCP2c2p1CEMDlZi62MZcfSvejgMySUHpVkwnRfHVg8JL_77s-Lpx_fH69vq7v7m5_W3uwoY7-aKPWOjSadN36MATgAJNxY0BcEaYVFwbDvDrO20ZGANl5rxpgGuRW-79rk9K65W3nzC7z2mWY0uAQ6DntDvk8r_k1JIxtoPQDvJZF6LZihboRB9ShGtCtGNOi6KEnWQS-3UKpc6yKUoVVmu3PZ1bcN88avDqBI4nACNiwizMt69T_AXnZqk4A</recordid><startdate>20170401</startdate><enddate>20170401</enddate><creator>Zhou, Jianhua</creator><creator>Hao, Bianzhi</creator><creator>Wang, Linben</creator><creator>Ma, Jianzhong</creator><creator>Cheng, Wenjing</creator><general>Elsevier B.V</general><scope>AAYXX</scope><scope>CITATION</scope><scope>7ST</scope><scope>C1K</scope><scope>SOI</scope><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope></search><sort><creationdate>20170401</creationdate><title>Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes</title><author>Zhou, Jianhua ; Hao, Bianzhi ; Wang, Linben ; Ma, Jianzhong ; Cheng, Wenjing</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-c475t-4be2a05ad66e8c70ce07dfca1c8428fe87e35d4ff5a94cfd79a4722c7a86f53b3</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2017</creationdate><topic>Acid fuchsin</topic><topic>Adsorption</topic><topic>Chitosan</topic><topic>Composite hydrogel</topic><topic>Degradation</topic><topic>Dyes</topic><topic>Hydrogels</topic><topic>Nano-TiO2</topic><topic>Nanostructure</topic><topic>Photocatalysis</topic><topic>Photocatalytic activity</topic><topic>Poly(N-isopropylacrylamide)</topic><topic>Surface chemistry</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Zhou, Jianhua</creatorcontrib><creatorcontrib>Hao, Bianzhi</creatorcontrib><creatorcontrib>Wang, Linben</creatorcontrib><creatorcontrib>Ma, Jianzhong</creatorcontrib><creatorcontrib>Cheng, Wenjing</creatorcontrib><collection>CrossRef</collection><collection>Environment Abstracts</collection><collection>Environmental Sciences and Pollution Management</collection><collection>Environment Abstracts</collection><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><jtitle>Separation and purification technology</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Zhou, Jianhua</au><au>Hao, Bianzhi</au><au>Wang, Linben</au><au>Ma, Jianzhong</au><au>Cheng, Wenjing</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes</atitle><jtitle>Separation and purification technology</jtitle><date>2017-04-01</date><risdate>2017</risdate><volume>176</volume><spage>193</spage><epage>199</epage><pages>193-199</pages><issn>1383-5866</issn><eissn>1873-3794</eissn><abstract>•Nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel was prepared by a two-step polymerization method.•Nano-TiO2 was used to give the photocatalytic activity of the composite hydrogel.•The composite hydrogel exhibited high efficiency of acid fuchsin dye removal rate under UV irradiation.
Nano-TiO2/chitosan/poly(N-isopropylacrylamide) (nano-TiO2/CS/PNIPAAm) composite hydrogel was prepared by a two-step polymerization method, and nano-TiO2 can endow the composite hydrogel with photocatalytic activity. The nano-TiO2/CS/PNIPAAm composite hydrogel was characterized by FT-IR and SEM. The properties of dye adsorption and photocatalytic degradation were investigated. The results indicated that dye adsorption was strongly influenced by solution pH and the acid fuchsin (AF) removal rate was maximum at pH=4. The dye removal rate decreased slightly with increasing temperature, and the composite hydrogel adsorbing AF dyes floated on the solution surface at 40°C and could be readily removed from the aqueous solution. Kinetics analysis indicated that the dye adsorption by nano-TiO2/CS/PNIPAAm composite hydrogel conformed to pseudo-second order model. Moreover, nano-TiO2/CS/PNIPAAm composite hydrogel exhibited high efficiency of photocatalytic degradation for AF dyes, and AF dye removal rate reached 90.5% under UV irradiation for 160min.</abstract><pub>Elsevier B.V</pub><doi>10.1016/j.seppur.2016.11.069</doi><tpages>7</tpages></addata></record> |
| fulltext | fulltext |
| identifier | ISSN: 1383-5866 |
| ispartof | Separation and purification technology, 2017-04, Vol.176, p.193-199 |
| issn | 1383-5866 1873-3794 |
| language | eng |
| recordid | cdi_proquest_miscellaneous_1879989443 |
| source | ScienceDirect Journals (5 years ago - present) |
| subjects | Acid fuchsin Adsorption Chitosan Composite hydrogel Degradation Dyes Hydrogels Nano-TiO2 Nanostructure Photocatalysis Photocatalytic activity Poly(N-isopropylacrylamide) Surface chemistry |
| title | Preparation and characterization of nano-TiO2/chitosan/poly(N-isopropylacrylamide) composite hydrogel and its application for removal of ionic dyes |
| url | https://sfx.bib-bvb.de/sfx_tum?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-08T01%3A02%3A18IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest_cross&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Preparation%20and%20characterization%20of%20nano-TiO2/chitosan/poly(N-isopropylacrylamide)%20composite%20hydrogel%20and%20its%20application%20for%20removal%20of%20ionic%20dyes&rft.jtitle=Separation%20and%20purification%20technology&rft.au=Zhou,%20Jianhua&rft.date=2017-04-01&rft.volume=176&rft.spage=193&rft.epage=199&rft.pages=193-199&rft.issn=1383-5866&rft.eissn=1873-3794&rft_id=info:doi/10.1016/j.seppur.2016.11.069&rft_dat=%3Cproquest_cross%3E1879989443%3C/proquest_cross%3E%3Curl%3E%3C/url%3E&disable_directlink=true&sfx.directlink=off&sfx.report_link=0&rft_id=info:oai/&rft_pqid=1859494751&rft_id=info:pmid/&rft_els_id=S1383586616308437&rfr_iscdi=true |