Investigating the role of amine in InP nanocrystal synthesis: destabilizing cluster intermediates by Z-type ligand displacement

The reaction of primary amines with In P (O CR) is found to remove In(O CR) subunits from In P (O CR) . This loss of Z-type ligands coincides with structural rearrangement to alleviate core strain and passivate phosphorus atoms. This result consolidates conflicting claims that primary amines both pr...

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Veröffentlicht in:	Chemical communications (Cambridge, England) England), 2017, Vol.53 (1), p.161-164
Hauptverfasser:	Gary, Dylan C, Petrone, Alessio, Li, Xiaosong, Cossairt, Brandi M
Format:	Artikel
Sprache:	eng
Schlagworte:	Amines Amines - chemistry Consolidation Conversion Core loss Displacement Ligands Nanocrystals Nanoparticles - chemistry Precursors
Online-Zugang:	Volltext
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