Fluorine‐Substituted Molecular Motors with a Quaternary Stereogenic Center

A series of unprecedented second generation molecular motors featuring a quaternary stereogenic center substituted with a fluorine atom has been synthesized. It is demonstrated that a seemingly benign replacement of the stereogenic hydrogen for a fluorine atom, regarded as a common substituent in ph...

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Veröffentlicht in:	Chemistry : a European journal 2017-05, Vol.23 (27), p.6643-6653
Hauptverfasser:	Štacko, Peter, Kistemaker, Jos C. M., Feringa, Ben L.
Format:	Artikel
Sprache:	eng
Schlagworte:	Chemistry Destabilization Fluorine Inversion Isomerization molecular motor Molecular motors Pharmacology photoisomerization quaternary Steric hindrance unidirectional
Online-Zugang:	Volltext
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