Potassium alum crystal derived from aluminum salt in water treatment sludge by nanofiltration

The major method used for the recovery of aluminum from water purification sludge is through acidification or alkalization, however, the cost of the acid and alkali limits the amount available for use, and thus results in the low concentration of dissolved aluminum salt; moreover, the metal ions and...

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Veröffentlicht in:Journal of material cycles and waste management 2015-07, Vol.17 (3), p.522-528
Hauptverfasser: Chi, Fung Hwa, Cheng, Wen Po, Tian, Dun Ren, Yu, Ruey Fang, Fu, Chi Hua
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container_issue 3
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container_title Journal of material cycles and waste management
container_volume 17
creator Chi, Fung Hwa
Cheng, Wen Po
Tian, Dun Ren
Yu, Ruey Fang
Fu, Chi Hua
description The major method used for the recovery of aluminum from water purification sludge is through acidification or alkalization, however, the cost of the acid and alkali limits the amount available for use, and thus results in the low concentration of dissolved aluminum salt; moreover, the metal ions and organic matter dissolved simultaneously in the process will also increase the difficulty in reuse. Therefore, this study used sulfuric acid to dissolve aluminum in the sludge from the water treatment plant, followed by the low price nanofiltration membranes to increase the concentration of aluminum ions, and then adding potassium sulfate to produce the potassium alum crystal, which has less impurity. The influences of the molar ratio of potassium to aluminum and the temperature on the recovery of crystals are investigated. The result showed that there was good crystal recovery when the molar ratio of potassium to aluminum is above 1.6, but the recovery rate decreased as the temperature increased.
doi_str_mv 10.1007/s10163-014-0269-3
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Therefore, this study used sulfuric acid to dissolve aluminum in the sludge from the water treatment plant, followed by the low price nanofiltration membranes to increase the concentration of aluminum ions, and then adding potassium sulfate to produce the potassium alum crystal, which has less impurity. The influences of the molar ratio of potassium to aluminum and the temperature on the recovery of crystals are investigated. 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moreover, the metal ions and organic matter dissolved simultaneously in the process will also increase the difficulty in reuse. Therefore, this study used sulfuric acid to dissolve aluminum in the sludge from the water treatment plant, followed by the low price nanofiltration membranes to increase the concentration of aluminum ions, and then adding potassium sulfate to produce the potassium alum crystal, which has less impurity. The influences of the molar ratio of potassium to aluminum and the temperature on the recovery of crystals are investigated. The result showed that there was good crystal recovery when the molar ratio of potassium to aluminum is above 1.6, but the recovery rate decreased as the temperature increased.</abstract><cop>Tokyo</cop><pub>Springer Japan</pub><doi>10.1007/s10163-014-0269-3</doi><tpages>7</tpages></addata></record>
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source Springer Nature - Complete Springer Journals
subjects Acidification
Alum
Aluminum
Civil Engineering
Crystals
Deodorants
Dissolution
Engineering
Environmental engineering
Environmental Management
Heavy metals
Metal concentrations
Metals
Nanofiltration
Nanotechnology
Organic matter
Original Article
Potassium
Recovery
Recycling
Salt
Sludge
Sulfuric acid
Waste Management/Waste Technology
Water filtration
Water purification
Water treatment
Water treatment plants
title Potassium alum crystal derived from aluminum salt in water treatment sludge by nanofiltration
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