Switchable surface structured hydrogel coatings

Switchable surface structures based on hydrogels are an emerging field in material science, microfluidics, soft robotics and anti-fouling. Here, we describe a novel method that uses a photo-cross-linkable terpolymer to create a hydrogel coating with a switchable surface structure. The terpolymer is...

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Veröffentlicht in:Soft matter 2017-03, Vol.13 (11), p.2239-2245
Hauptverfasser: Kommeren, Sander, Dongmo, J, Bastiaansen, C. W. M
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container_title Soft matter
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creator Kommeren, Sander
Dongmo, J
Bastiaansen, C. W. M
description Switchable surface structures based on hydrogels are an emerging field in material science, microfluidics, soft robotics and anti-fouling. Here, we describe a novel method that uses a photo-cross-linkable terpolymer to create a hydrogel coating with a switchable surface structure. The terpolymer is based on poly( N -isopropylacrylamide) (PNIPAm) and it is shown that simple coating technologies like slit die coating can be used under ambient conditions. It is also shown that the swelling ratio of the coating is controlled by the energy dose of ultraviolet (UV) light. Simple and complex surface structures were created using respectively single or multiple UV illumination steps through masks and it is shown that the hydrogel coatings can be reversibly switched from a structured state to a flat state with temperature. We describe a novel method of producing switchable surface structures on hydrogel coatings and we show a novel characterization method for in situ measurements: confocal microscopy.
doi_str_mv 10.1039/c7sm00195a
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source Royal Society Of Chemistry Journals 2008-; Alma/SFX Local Collection
subjects Coatings
Hydrogels
Illumination
Light (illumination)
Microfluidics
Slits
Surface structure
Terpolymers
title Switchable surface structured hydrogel coatings
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