Möbius Aromatic [28]Hexaphyrin Germanium(IV) and Tin(IV) Complexes: Efficient Formation of Triplet Excited States

[28]Hexaphyrin GeIV and SnIV complexes were synthesized in high yields by reactions of [28]hexaphyrin with GeCl4 or SnCl4 in the presence of triethylamine. Both complexes display distinct 28π Möbius aromatic character and possess a trigonal bipyramidal geometry at the central GeIV or SnIV atom. The...

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Veröffentlicht in:	Angewandte Chemie International Edition 2017-03, Vol.56 (14), p.3982-3986
Hauptverfasser:	Izawa, Mondo, Kim, Taeyeon, Ishida, Shin‐ichiro, Tanaka, Takayuki, Mori, Tadashi, Kim, Dongho, Osuka, Atsuhiro
Format:	Artikel
Sprache:	eng
Schlagworte:	Baird rule Chemical synthesis chiral resolution Germanium intersystem crossing Möbius aromaticity Nucleophiles Phenols porphyrinoids Thiophenol Tin Triethylamine
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