Catalytic Enantioselective Transformations Involving C–H Bond Cleavage by Transition-Metal Complexes

The development of new methods for the direct functionalization of unactivated C–H bonds is ushering in a paradigm shift in the field of retrosynthetic analysis. In particular, the catalytic enantioselective functionalization of C–H bonds represents a highly atom- and step-economic approach toward t...

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Veröffentlicht in:	Chemical reviews 2017-07, Vol.117 (13), p.8908-8976
Hauptverfasser:	Newton, Christopher G, Wang, Shou-Guo, Oliveira, Caio C, Cramer, Nicolai
Format:	Artikel
Sprache:	eng
Schlagworte:	Asymmetry Carbon Catalysis Chemistry Coordination compounds Ductile-brittle transition Fracture mechanics Hydrogen bonds Metal complexes Metals Stereochemistry Stereoselectivity
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