Benchmark Ditopic Binding of Cl− and Cs+ by the Macrocycle Hexacyclen

The ditopic binding of organic and inorganic anions and cations constitutes a distinct feature of polyazamacrocycles that underlies their action as intermediate docking and exchange ionophoric sites for tailored supramolecular synthesis and sensors. This work investigates the Cl− and Cs+ complexes f...

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Veröffentlicht in:	Chemphyschem 2017-05, Vol.18 (10), p.1324-1332
Hauptverfasser:	Avilés‐Moreno, Juan Ramón, Berden, Giel, Oomens, Jos, Martínez‐Haya, Bruno
Format:	Artikel
Sprache:	eng
Schlagworte:	Anions Benchmarks Binding Cations crown compounds Infrared spectroscopy Ion pairs ionophores IR spectroscopy molecular modeling Polyamines Quantum chemistry Ring structures Room temperature Spectrum analysis
Online-Zugang:	Volltext
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